Preparation of Tri- and Difluoromethylsilanes via an Unusual Magnesium Metal-Mediated Reductive Tri- and Difluoromethylation of Chlorosilanes Using Tri- and Difluoromethyl Sulfides, Sulfoxides, and Sulfones

A new and efficient method for the preparation of tri- and difluoromethylsilanes using magnesium metal-mediated reductive tri- and difluoromethylation of chlorosilanes is reported using tri- and difluoromethyl sulfides, sulfoxides, and sulfones. The byproduct of the process is diphenyl disulfide. Si...

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Veröffentlicht in:	Journal of organic chemistry 2003-05, Vol.68 (11), p.4457-4463
Hauptverfasser:	Prakash, G. K. Surya, Hu, Jinbo, Olah, George A
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemistry Exact sciences and technology Organic chemistry Organometalloidal and organometallic compounds Preparations and properties Si derivatives
Online-Zugang:	Volltext
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