The Electronic Structure and Photochemistry of Group 6 Bimetallic (Fischer) Carbene Complexes: Beyond the Photocarbonylation Reaction

The UV spectra of Group 6 metal carbene complexes bearing a CpM(CO)3 (Cp=cyclopentadienyl) moiety bonded to the carbene carbon atom exhibit a redshift of the absorption maxima at higher wavelengths with respect to the parent monometallic complexes. This redshift is partly due to a higher occupation...

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Veröffentlicht in:	Chemistry : a European journal 2010-06, Vol.16 (22), p.6616-6624
Hauptverfasser:	Lage, Marta L., Fernández, Israel, Mancheño, María J., Gómez-Gallego, Mar, Sierra, Miguel A.
Format:	Artikel
Sprache:	eng
Schlagworte:	bimetallic complexes carbenes density functional calculations electronic structure photochemistry
Online-Zugang:	Volltext
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