Ozone- and Photon-Enhanced Atmospheric Sulfidation of Copper
The sulfidation of materials upon exposure to the atmosphere has traditionally been attributed entirely to reactions with sulfur-containing gases and water vapor. New laboratory results demonstrate that the sulfidation of polycrystalline copper can be markedly enhanced both by solar radiation and by...
Gespeichert in:
| Veröffentlicht in: | Science (American Association for the Advancement of Science) 1984-05, Vol.224 (4649), p.599-601 |
|---|---|
| Hauptverfasser: | , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 601 |
|---|---|
| container_issue | 4649 |
| container_start_page | 599 |
| container_title | Science (American Association for the Advancement of Science) |
| container_volume | 224 |
| creator | Graedel, T. E. Franey, J. P. Kammlott, G. W. |
| description | The sulfidation of materials upon exposure to the atmosphere has traditionally been attributed entirely to reactions with sulfur-containing gases and water vapor. New laboratory results demonstrate that the sulfidation of polycrystalline copper can be markedly enhanced both by solar radiation and by the ubiquitous atmospheric ozone, thus indicating that the high rates of corrosion in urban areas are a result of a complex sequence of multicomponent photochemical processes. |
| doi_str_mv | 10.1126/science.224.4649.599 |
| format | Article |
| fullrecord | <record><control><sourceid>gale_osti_</sourceid><recordid>TN_cdi_proquest_miscellaneous_733236993</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><galeid>A3264042</galeid><jstor_id>1692925</jstor_id><sourcerecordid>A3264042</sourcerecordid><originalsourceid>FETCH-LOGICAL-c534t-7c751725375a597861263c2e05386ad2f415d862e2577e775a09866bcc3cf6bf3</originalsourceid><addsrcrecordid>eNqN0k2LEzEYB_Agilur32CRwcse1qmZvE7ASy1rXShWWPUa0swz7SwzyTjJgPrpzTKFXaGHkkMgzy8hT_JH6LLAi6Ig4kOwDTgLC0LYggmmFlypZ2hWYMVzRTB9jmYYU5GXWPIL9CqEe4xTTdGX6KKQJS0pZzP0cfvXO8gz46rs28FH7_IbdzDp4Cpbxs6H_gBDY7O7sa2bysTGu8zX2cr3PQyv0YvatAHeHOc5-vH55vvqS77Zrm9Xy01uOWUxl1byQhJOJTdcyVKk61NLAHNaClORmhW8KgUBwqUEmRRWpRA7a6mtxa6mc_RuOteH2OjUeAR7sN45sFELVTKWupmjqwn1g_81Qoi6a4KFtjUO_Bi0pJRQoRRN8nqSe9OCblzt42DsHhwMpk2vUTdpeUmJYJiRpN-f0GlU0DX2BL_6jycR4XfcmzEEfXv39Vy5_Xmu_LQ-U5brzVN5fUpa37awB53-b7V9qtmk7eBDGKDW_dB0ZvijC6wf4qiPcdQpjvohjjrFMW17e_yTcddB9bjpmL8ELidwH6IfHutCEZUC8w8Bz9-9</addsrcrecordid><sourcetype>Open Access Repository</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>733236993</pqid></control><display><type>article</type><title>Ozone- and Photon-Enhanced Atmospheric Sulfidation of Copper</title><source>American Association for the Advancement of Science</source><source>Jstor Complete Legacy</source><creator>Graedel, T. E. ; Franey, J. P. ; Kammlott, G. W.</creator><creatorcontrib>Graedel, T. E. ; Franey, J. P. ; Kammlott, G. W. ; AT and T Bell Laboratories, Murray Hill, NJ</creatorcontrib><description>The sulfidation of materials upon exposure to the atmosphere has traditionally been attributed entirely to reactions with sulfur-containing gases and water vapor. New laboratory results demonstrate that the sulfidation of polycrystalline copper can be markedly enhanced both by solar radiation and by the ubiquitous atmospheric ozone, thus indicating that the high rates of corrosion in urban areas are a result of a complex sequence of multicomponent photochemical processes.</description><identifier>ISSN: 0036-8075</identifier><identifier>EISSN: 1095-9203</identifier><identifier>DOI: 10.1126/science.224.4649.599</identifier><identifier>PMID: 17838354</identifier><language>eng</language><publisher>United States: The American Association for the Advancement of Science</publisher><subject>500200 - Environment, Atmospheric- Chemicals Monitoring & Transport- (-1989) ; AIR POLLUTION ; ATMOSPHERIC CHEMISTRY ; Atmospherics ; CHEMICAL REACTIONS ; CHEMISTRY ; COPPER ; Copper (Metal) ; CORROSION ; Corrosion (Chemistry) ; Corrosion and anti-corrosives ; Electrochemistry ; ELEMENTARY PARTICLES ; ELEMENTS ; ENVIRONMENTAL EFFECTS ; ENVIRONMENTAL SCIENCES ; Gases ; Incident radiation ; Maintenance and repair ; MASSLESS PARTICLES ; Material films ; Materials ; METALS ; OZONE ; PHOTOCHEMICAL REACTIONS ; PHOTONS ; POLLUTION ; RADIATIONS ; SOLAR RADIATION ; STELLAR RADIATION ; SULFIDATION ; Sulfides ; TRANSITION ELEMENTS ; URBAN AREAS</subject><ispartof>Science (American Association for the Advancement of Science), 1984-05, Vol.224 (4649), p.599-601</ispartof><rights>Copyright 1984 The American Association for the Advancement of Science</rights><rights>COPYRIGHT 1984 American Association for the Advancement of Science</rights><rights>COPYRIGHT 1984 American Association for the Advancement of Science</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c534t-7c751725375a597861263c2e05386ad2f415d862e2577e775a09866bcc3cf6bf3</citedby><cites>FETCH-LOGICAL-c534t-7c751725375a597861263c2e05386ad2f415d862e2577e775a09866bcc3cf6bf3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://www.jstor.org/stable/pdf/1692925$$EPDF$$P50$$Gjstor$$H</linktopdf><linktohtml>$$Uhttps://www.jstor.org/stable/1692925$$EHTML$$P50$$Gjstor$$H</linktohtml><link.rule.ids>314,777,781,800,882,2871,2872,27905,27906,57998,58231</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/17838354$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink><backlink>$$Uhttps://www.osti.gov/biblio/6984438$$D View this record in Osti.gov$$Hfree_for_read</backlink></links><search><creatorcontrib>Graedel, T. E.</creatorcontrib><creatorcontrib>Franey, J. P.</creatorcontrib><creatorcontrib>Kammlott, G. W.</creatorcontrib><creatorcontrib>AT and T Bell Laboratories, Murray Hill, NJ</creatorcontrib><title>Ozone- and Photon-Enhanced Atmospheric Sulfidation of Copper</title><title>Science (American Association for the Advancement of Science)</title><addtitle>Science</addtitle><description>The sulfidation of materials upon exposure to the atmosphere has traditionally been attributed entirely to reactions with sulfur-containing gases and water vapor. New laboratory results demonstrate that the sulfidation of polycrystalline copper can be markedly enhanced both by solar radiation and by the ubiquitous atmospheric ozone, thus indicating that the high rates of corrosion in urban areas are a result of a complex sequence of multicomponent photochemical processes.</description><subject>500200 - Environment, Atmospheric- Chemicals Monitoring & Transport- (-1989)</subject><subject>AIR POLLUTION</subject><subject>ATMOSPHERIC CHEMISTRY</subject><subject>Atmospherics</subject><subject>CHEMICAL REACTIONS</subject><subject>CHEMISTRY</subject><subject>COPPER</subject><subject>Copper (Metal)</subject><subject>CORROSION</subject><subject>Corrosion (Chemistry)</subject><subject>Corrosion and anti-corrosives</subject><subject>Electrochemistry</subject><subject>ELEMENTARY PARTICLES</subject><subject>ELEMENTS</subject><subject>ENVIRONMENTAL EFFECTS</subject><subject>ENVIRONMENTAL SCIENCES</subject><subject>Gases</subject><subject>Incident radiation</subject><subject>Maintenance and repair</subject><subject>MASSLESS PARTICLES</subject><subject>Material films</subject><subject>Materials</subject><subject>METALS</subject><subject>OZONE</subject><subject>PHOTOCHEMICAL REACTIONS</subject><subject>PHOTONS</subject><subject>POLLUTION</subject><subject>RADIATIONS</subject><subject>SOLAR RADIATION</subject><subject>STELLAR RADIATION</subject><subject>SULFIDATION</subject><subject>Sulfides</subject><subject>TRANSITION ELEMENTS</subject><subject>URBAN AREAS</subject><issn>0036-8075</issn><issn>1095-9203</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1984</creationdate><recordtype>article</recordtype><recordid>eNqN0k2LEzEYB_Agilur32CRwcse1qmZvE7ASy1rXShWWPUa0swz7SwzyTjJgPrpzTKFXaGHkkMgzy8hT_JH6LLAi6Ig4kOwDTgLC0LYggmmFlypZ2hWYMVzRTB9jmYYU5GXWPIL9CqEe4xTTdGX6KKQJS0pZzP0cfvXO8gz46rs28FH7_IbdzDp4Cpbxs6H_gBDY7O7sa2bysTGu8zX2cr3PQyv0YvatAHeHOc5-vH55vvqS77Zrm9Xy01uOWUxl1byQhJOJTdcyVKk61NLAHNaClORmhW8KgUBwqUEmRRWpRA7a6mtxa6mc_RuOteH2OjUeAR7sN45sFELVTKWupmjqwn1g_81Qoi6a4KFtjUO_Bi0pJRQoRRN8nqSe9OCblzt42DsHhwMpk2vUTdpeUmJYJiRpN-f0GlU0DX2BL_6jycR4XfcmzEEfXv39Vy5_Xmu_LQ-U5brzVN5fUpa37awB53-b7V9qtmk7eBDGKDW_dB0ZvijC6wf4qiPcdQpjvohjjrFMW17e_yTcddB9bjpmL8ELidwH6IfHutCEZUC8w8Bz9-9</recordid><startdate>19840511</startdate><enddate>19840511</enddate><creator>Graedel, T. E.</creator><creator>Franey, J. P.</creator><creator>Kammlott, G. W.</creator><general>The American Association for the Advancement of Science</general><general>American Association for the Advancement of Science</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>8GL</scope><scope>IBG</scope><scope>IOV</scope><scope>ISN</scope><scope>7X8</scope><scope>OTOTI</scope></search><sort><creationdate>19840511</creationdate><title>Ozone- and Photon-Enhanced Atmospheric Sulfidation of Copper</title><author>Graedel, T. E. ; Franey, J. P. ; Kammlott, G. W.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c534t-7c751725375a597861263c2e05386ad2f415d862e2577e775a09866bcc3cf6bf3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1984</creationdate><topic>500200 - Environment, Atmospheric- Chemicals Monitoring & Transport- (-1989)</topic><topic>AIR POLLUTION</topic><topic>ATMOSPHERIC CHEMISTRY</topic><topic>Atmospherics</topic><topic>CHEMICAL REACTIONS</topic><topic>CHEMISTRY</topic><topic>COPPER</topic><topic>Copper (Metal)</topic><topic>CORROSION</topic><topic>Corrosion (Chemistry)</topic><topic>Corrosion and anti-corrosives</topic><topic>Electrochemistry</topic><topic>ELEMENTARY PARTICLES</topic><topic>ELEMENTS</topic><topic>ENVIRONMENTAL EFFECTS</topic><topic>ENVIRONMENTAL SCIENCES</topic><topic>Gases</topic><topic>Incident radiation</topic><topic>Maintenance and repair</topic><topic>MASSLESS PARTICLES</topic><topic>Material films</topic><topic>Materials</topic><topic>METALS</topic><topic>OZONE</topic><topic>PHOTOCHEMICAL REACTIONS</topic><topic>PHOTONS</topic><topic>POLLUTION</topic><topic>RADIATIONS</topic><topic>SOLAR RADIATION</topic><topic>STELLAR RADIATION</topic><topic>SULFIDATION</topic><topic>Sulfides</topic><topic>TRANSITION ELEMENTS</topic><topic>URBAN AREAS</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Graedel, T. E.</creatorcontrib><creatorcontrib>Franey, J. P.</creatorcontrib><creatorcontrib>Kammlott, G. W.</creatorcontrib><creatorcontrib>AT and T Bell Laboratories, Murray Hill, NJ</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>Gale In Context: High School</collection><collection>Gale In Context: Biography</collection><collection>Gale In Context: Opposing Viewpoints</collection><collection>Gale In Context: Canada</collection><collection>MEDLINE - Academic</collection><collection>OSTI.GOV</collection><jtitle>Science (American Association for the Advancement of Science)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Graedel, T. E.</au><au>Franey, J. P.</au><au>Kammlott, G. W.</au><aucorp>AT and T Bell Laboratories, Murray Hill, NJ</aucorp><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Ozone- and Photon-Enhanced Atmospheric Sulfidation of Copper</atitle><jtitle>Science (American Association for the Advancement of Science)</jtitle><addtitle>Science</addtitle><date>1984-05-11</date><risdate>1984</risdate><volume>224</volume><issue>4649</issue><spage>599</spage><epage>601</epage><pages>599-601</pages><issn>0036-8075</issn><eissn>1095-9203</eissn><abstract>The sulfidation of materials upon exposure to the atmosphere has traditionally been attributed entirely to reactions with sulfur-containing gases and water vapor. New laboratory results demonstrate that the sulfidation of polycrystalline copper can be markedly enhanced both by solar radiation and by the ubiquitous atmospheric ozone, thus indicating that the high rates of corrosion in urban areas are a result of a complex sequence of multicomponent photochemical processes.</abstract><cop>United States</cop><pub>The American Association for the Advancement of Science</pub><pmid>17838354</pmid><doi>10.1126/science.224.4649.599</doi><tpages>3</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0036-8075 |
| ispartof | Science (American Association for the Advancement of Science), 1984-05, Vol.224 (4649), p.599-601 |
| issn | 0036-8075 1095-9203 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_733236993 |
| source | American Association for the Advancement of Science; Jstor Complete Legacy |
| subjects | 500200 - Environment, Atmospheric- Chemicals Monitoring & Transport- (-1989) AIR POLLUTION ATMOSPHERIC CHEMISTRY Atmospherics CHEMICAL REACTIONS CHEMISTRY COPPER Copper (Metal) CORROSION Corrosion (Chemistry) Corrosion and anti-corrosives Electrochemistry ELEMENTARY PARTICLES ELEMENTS ENVIRONMENTAL EFFECTS ENVIRONMENTAL SCIENCES Gases Incident radiation Maintenance and repair MASSLESS PARTICLES Material films Materials METALS OZONE PHOTOCHEMICAL REACTIONS PHOTONS POLLUTION RADIATIONS SOLAR RADIATION STELLAR RADIATION SULFIDATION Sulfides TRANSITION ELEMENTS URBAN AREAS |
| title | Ozone- and Photon-Enhanced Atmospheric Sulfidation of Copper |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-21T05%3A16%3A37IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-gale_osti_&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Ozone-%20and%20Photon-Enhanced%20Atmospheric%20Sulfidation%20of%20Copper&rft.jtitle=Science%20(American%20Association%20for%20the%20Advancement%20of%20Science)&rft.au=Graedel,%20T.%20E.&rft.aucorp=AT%20and%20T%20Bell%20Laboratories,%20Murray%20Hill,%20NJ&rft.date=1984-05-11&rft.volume=224&rft.issue=4649&rft.spage=599&rft.epage=601&rft.pages=599-601&rft.issn=0036-8075&rft.eissn=1095-9203&rft_id=info:doi/10.1126/science.224.4649.599&rft_dat=%3Cgale_osti_%3EA3264042%3C/gale_osti_%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=733236993&rft_id=info:pmid/17838354&rft_galeid=A3264042&rft_jstor_id=1692925&rfr_iscdi=true |