Disorder in Al-Li-Cu and Al-Mn-Si Icosahedral Alloys

Faceted dendrites of icosahedral Al$_{6}$Li$_{3}$Cu have been studied by high-resolution x-ray scattering. The samples display long-range icosahedral symmetry both in their diffraction patterns and in their macroscopic morphology. Despite the appearance of well-defined facets, the samples have a hig...

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Veröffentlicht in:Science (American Association for the Advancement of Science) 1987-10, Vol.238 (4827), p.660-663
Hauptverfasser: Heiney, P. A., Bancel, P. A., Horn, P. M., Jordan, J. L., LaPlaca, S., Angilello, J., Gayle, F. W.
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container_end_page 663
container_issue 4827
container_start_page 660
container_title Science (American Association for the Advancement of Science)
container_volume 238
creator Heiney, P. A.
Bancel, P. A.
Horn, P. M.
Jordan, J. L.
LaPlaca, S.
Angilello, J.
Gayle, F. W.
description Faceted dendrites of icosahedral Al$_{6}$Li$_{3}$Cu have been studied by high-resolution x-ray scattering. The samples display long-range icosahedral symmetry both in their diffraction patterns and in their macroscopic morphology. Despite the appearance of well-defined facets, the samples have a high degree of atomic disorder. The Bragg peaks have symmetry-dependent shapes and widths that scale linearly with G$_{\perp}$ (phason momentum). The peak widths are surprisingly similar to those found in icosahedral Al-Mn-Si alloys in both their absolute magnitude and their dependence on G$_{\perp}$. The origin of these features in models for the icosahedral phase is discussed.
doi_str_mv 10.1126/science.238.4827.660
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subjects Alloys
Applied sciences
Chemistry
Crystal lattices
Crystals
Dendrites
Diffraction
Electromagnetic scattering
Electromagnetic waves
Exact sciences and technology
Icosahedrons
Mathematical lattices
Other techniques and industries
Rapid quenching
Scattering
Symmetry
Tiling
Vertices
Wave diffraction
X-ray diffraction
X-rays
title Disorder in Al-Li-Cu and Al-Mn-Si Icosahedral Alloys
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