Adhesive Electroless Metallization of Fluoropolymeric Substrates
A process for producing patterned metal deposits on fluoropolymeric substrates is described. A metal ion-chelating organosilane is chemisorbed by self-assembly onto a fluoropolymer surface after radio-frequency glow discharge plasma surface hydroxylation. Positional modulation of the surface hydroph...
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| Veröffentlicht in: | Science (American Association for the Advancement of Science) 1993-12, Vol.262 (5140), p.1711-1712 |
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| container_end_page | 1712 |
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| container_issue | 5140 |
| container_start_page | 1711 |
| container_title | Science (American Association for the Advancement of Science) |
| container_volume | 262 |
| creator | Vargo, Terrence G. Gardella, Joseph A. Calvert, Jeffrey M. Chen, Mu-San |
| description | A process for producing patterned metal deposits on fluoropolymeric substrates is described. A metal ion-chelating organosilane is chemisorbed by self-assembly onto a fluoropolymer surface after radio-frequency glow discharge plasma surface hydroxylation. Positional modulation of the surface hydrophobicity is illustrated by wetting. The silane covalently binds an aqueous palladium catalyst and subsequent electroless deposition yields homogeneous or patterned metal deposits that exhibit excellent adhesion to the fluoropolymer. |
| doi_str_mv | 10.1126/science.262.5140.1711 |
| format | Article |
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A metal ion-chelating organosilane is chemisorbed by self-assembly onto a fluoropolymer surface after radio-frequency glow discharge plasma surface hydroxylation. Positional modulation of the surface hydrophobicity is illustrated by wetting. 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A metal ion-chelating organosilane is chemisorbed by self-assembly onto a fluoropolymer surface after radio-frequency glow discharge plasma surface hydroxylation. Positional modulation of the surface hydrophobicity is illustrated by wetting. The silane covalently binds an aqueous palladium catalyst and subsequent electroless deposition yields homogeneous or patterned metal deposits that exhibit excellent adhesion to the fluoropolymer.</description><subject>Adhesion</subject><subject>Adhesives</subject><subject>Applied sciences</subject><subject>Chemicals</subject><subject>Coating, metallization, dyeing</subject><subject>Electroless plating</subject><subject>Exact sciences and technology</subject><subject>Fluoropolymers</subject><subject>Liquids</subject><subject>Machinery and processing</subject><subject>Material films</subject><subject>Materials</subject><subject>Metallizing</subject><subject>Plastics</subject><subject>Polymer industry, paints, wood</subject><subject>Reagents</subject><subject>Research facilities</subject><subject>Technology of polymers</subject><subject>Wetting</subject><issn>0036-8075</issn><issn>1095-9203</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1993</creationdate><recordtype>article</recordtype><recordid>eNqN0stuEzEUBmALgWhaeANAs0Aqi07wZS72jhC1oVIgiwJby-M5E1w549T2IMrT4yijokhZRF5Y8vmOZfn8CL0leEoIrT4GbaDXMKUVnZakSKc1Ic_QhGBR5oJi9hxNMGZVznFdnqHzEO4xTjXBXqIzUtec1FxM0KdZ-wuC-Q3ZtQUdvbMQQvYVorLW_FXRuD5zXXZjB-fd1tnHDXijs7uhCdGrCOEVetEpG-D1uF-gHzfX3-df8uVqcTufLXNdCRHzVgmBmW4LWjaEN4Rg4NBpUuGiwJo1baV4rXBFOloAbgQHwdtSKNbyimrcsgt0ub93693DACHKjQkarFU9uCHImjGKafqIJK_2cq0sSNN3Lr1Ur6EHr6zroTPpeEaKirGS08TzIzytFjZGH_MfDnwiEf7EtRpCkLd3306mq58n08-LUylfLA_o1TGqnbWwBpkGNF8d8HLPtXcheOjk1puN8o-SYLlLnRxTJ1Pq5C51cpe61PdunM3QbKD93zXGLIH3I1BBK9t51WsTnhzjBeN8d8-bPbsP0fmnMuW8xJyxf1Wo5jo</recordid><startdate>19931210</startdate><enddate>19931210</enddate><creator>Vargo, Terrence G.</creator><creator>Gardella, Joseph A.</creator><creator>Calvert, Jeffrey M.</creator><creator>Chen, Mu-San</creator><general>American Society for the Advancement of Science</general><general>American Association for the Advancement of Science</general><scope>IQODW</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>8GL</scope><scope>IBG</scope><scope>IOV</scope><scope>ISN</scope><scope>7X8</scope></search><sort><creationdate>19931210</creationdate><title>Adhesive Electroless Metallization of Fluoropolymeric Substrates</title><author>Vargo, Terrence G. ; Gardella, Joseph A. ; Calvert, Jeffrey M. ; Chen, Mu-San</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c699t-da9903cd425b18b110e8efc160440c3bd6a87a061f24e0b98e98d59a3d862c0d3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1993</creationdate><topic>Adhesion</topic><topic>Adhesives</topic><topic>Applied sciences</topic><topic>Chemicals</topic><topic>Coating, metallization, dyeing</topic><topic>Electroless plating</topic><topic>Exact sciences and technology</topic><topic>Fluoropolymers</topic><topic>Liquids</topic><topic>Machinery and processing</topic><topic>Material films</topic><topic>Materials</topic><topic>Metallizing</topic><topic>Plastics</topic><topic>Polymer industry, paints, wood</topic><topic>Reagents</topic><topic>Research facilities</topic><topic>Technology of polymers</topic><topic>Wetting</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Vargo, Terrence G.</creatorcontrib><creatorcontrib>Gardella, Joseph A.</creatorcontrib><creatorcontrib>Calvert, Jeffrey M.</creatorcontrib><creatorcontrib>Chen, Mu-San</creatorcontrib><collection>Pascal-Francis</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>Gale In Context: High School</collection><collection>Gale In Context: Biography</collection><collection>Gale In Context: Opposing Viewpoints</collection><collection>Gale In Context: Canada</collection><collection>MEDLINE - Academic</collection><jtitle>Science (American Association for the Advancement of Science)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Vargo, Terrence G.</au><au>Gardella, Joseph A.</au><au>Calvert, Jeffrey M.</au><au>Chen, Mu-San</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Adhesive Electroless Metallization of Fluoropolymeric Substrates</atitle><jtitle>Science (American Association for the Advancement of Science)</jtitle><addtitle>Science</addtitle><date>1993-12-10</date><risdate>1993</risdate><volume>262</volume><issue>5140</issue><spage>1711</spage><epage>1712</epage><pages>1711-1712</pages><issn>0036-8075</issn><eissn>1095-9203</eissn><coden>SCIEAS</coden><abstract>A process for producing patterned metal deposits on fluoropolymeric substrates is described. A metal ion-chelating organosilane is chemisorbed by self-assembly onto a fluoropolymer surface after radio-frequency glow discharge plasma surface hydroxylation. Positional modulation of the surface hydrophobicity is illustrated by wetting. The silane covalently binds an aqueous palladium catalyst and subsequent electroless deposition yields homogeneous or patterned metal deposits that exhibit excellent adhesion to the fluoropolymer.</abstract><cop>Washington, DC</cop><pub>American Society for the Advancement of Science</pub><pmid>17781789</pmid><doi>10.1126/science.262.5140.1711</doi><tpages>2</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0036-8075 |
| ispartof | Science (American Association for the Advancement of Science), 1993-12, Vol.262 (5140), p.1711-1712 |
| issn | 0036-8075 1095-9203 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_733202140 |
| source | American Association for the Advancement of Science; Jstor Complete Legacy |
| subjects | Adhesion Adhesives Applied sciences Chemicals Coating, metallization, dyeing Electroless plating Exact sciences and technology Fluoropolymers Liquids Machinery and processing Material films Materials Metallizing Plastics Polymer industry, paints, wood Reagents Research facilities Technology of polymers Wetting |
| title | Adhesive Electroless Metallization of Fluoropolymeric Substrates |
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