Highly Selective Ylide-Initiated Michael Addition/Cyclization Reaction for Synthesis of Cyclohexadiene Epoxide and Vinylcyclopropane Derivatives
On the basis of the reactions of camphor-derived sulfur ylide with α,β-unsaturated ketone, highly efficient and selective synthesis of optically active cyclohexadiene epoxides and vinylcyclopropanes with excellent diastereoselectivities, moderate to high enantioselectivities, and yields has been ach...
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| Veröffentlicht in: | Journal of organic chemistry 2010-05, Vol.75 (10), p.3454-3457 |
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| container_end_page | 3457 |
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| container_issue | 10 |
| container_start_page | 3454 |
| container_title | Journal of organic chemistry |
| container_volume | 75 |
| creator | Zhu, Ben-Hu Zhou, Rui Zheng, Jun-Cheng Deng, Xian-Ming Sun, Xiu-Li Shen, Qi Tang, Yong |
| description | On the basis of the reactions of camphor-derived sulfur ylide with α,β-unsaturated ketone, highly efficient and selective synthesis of optically active cyclohexadiene epoxides and vinylcyclopropanes with excellent diastereoselectivities, moderate to high enantioselectivities, and yields has been achieved. |
| doi_str_mv | 10.1021/jo100306z |
| format | Article |
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| identifier | ISSN: 0022-3263 |
| ispartof | Journal of organic chemistry, 2010-05, Vol.75 (10), p.3454-3457 |
| issn | 0022-3263 1520-6904 |
| language | eng |
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| source | MEDLINE; ACS Publications |
| subjects | Alicyclic compounds Alicyclic compounds, terpenoids, prostaglandins, steroids Chemistry Cyclization Cyclohexenes - chemical synthesis Cyclohexenes - chemistry Cyclopropanes - chemical synthesis Cyclopropanes - chemistry Epoxy Compounds - chemical synthesis Epoxy Compounds - chemistry Exact sciences and technology Heterocyclic compounds Heterocyclic compounds with o, s, se, te hetero atom and condensed derivatives Molecular Structure Organic chemistry Preparations and properties Stereoisomerism Terpenoids Vinyl Compounds - chemical synthesis Vinyl Compounds - chemistry |
| title | Highly Selective Ylide-Initiated Michael Addition/Cyclization Reaction for Synthesis of Cyclohexadiene Epoxide and Vinylcyclopropane Derivatives |
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