Redox Chemistry and Electronic Properties of 2,3,5,6-Tetrakis(2-pyridyl)pyrazine-Bridged Diruthenium Complexes Controlled by N,C,N′-BisCyclometalated Ligands

To investigate the consequences of cyclometalation for electronic communication in dinuclear ruthenium complexes, a series of 2,3,5,6-tetrakis(2-pyridyl)pyrazine (tppz) bridged diruthenium complexes was prepared and studied. These complexes have a central tppz ligand bridging via nitrogen-to-rutheni...

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Veröffentlicht in:	Inorganic chemistry 2009-07, Vol.48 (13), p.5685-5696
Hauptverfasser:	Wadman, Sipke H, Havenith, Remco W. A, Hartl, František, Lutz, Martin, Spek, Anthony L, van Klink, Gerard P. M, van Koten, Gerard
Format:	Artikel
Sprache:	eng
Schlagworte:	Ligands Metals - chemistry Oxidation-Reduction Pyrazines - chemistry Ruthenium Compounds - chemistry Spectroscopy, Near-Infrared
Online-Zugang:	Volltext
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