Rearrangements and Intramolecular Diels−Alder Reactions of Normal and Vinylogous Aza-Morita−Baylis−Hillman Products Leading to Isoindoline Derivatives

Aza-Morita−Baylis−Hillman (aza-MBH) products derived from arylimines and methyl acrylate or acrylonitrile were N-alkylated with (E)-5-bromopenta-1,3-diene, and the resulting trienes were subjected to intramolecular Diels−Alder (IMDA) cyloadditions to afford the corresponding trans- and cis-fused tet...

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Veröffentlicht in:	Journal of organic chemistry 2010-06, Vol.75 (11), p.3751-3760
Hauptverfasser:	Clary, Kristen N, Parvez, Masood, Back, Thomas G
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemistry Exact sciences and technology Heterocyclic compounds Heterocyclic compounds with only one n hetero atom and condensed derivatives Organic chemistry Preparations and properties
Online-Zugang:	Volltext
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