Rh(II) and Rh(I) Two-Legged Piano-Stool Complexes:  Structure, Reactivity, and Electronic Properties

The ligand 1,4-bis[4-(diphenylphosphino)butyl]-2,3,5,6-tetramethylbenzene, 3, was used to synthesize a mononuclear Rh(II) complex [(η1:η6:η1-1,4-bis[4-(diphenylphosphino)butyl]-2,3,5,6-tetramethylbenzene)Rh][PF6]2, 6 +, in a two-legged piano-stool geometry. The structural and electronic properties o...

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Veröffentlicht in:	Inorganic chemistry 2003-05, Vol.42 (10), p.3245-3255
Hauptverfasser:	Dixon, Felicia M, Masar, Martin S, Doan, Peter E, Farrell, Joshua R, Arnold, Frederick P, Mirkin, Chad A, Incarvito, Christopher D, Zakharov, Lev N, Rheingold, Arnold L
Format:	Artikel
Sprache:	eng
Schlagworte:	Crystallography, X-Ray Electrochemistry Electron Spin Resonance Spectroscopy Ligands Molecular Conformation Molecular Structure Organometallic Compounds - chemical synthesis Organometallic Compounds - chemistry Oxidation-Reduction Rhodium - chemistry
Online-Zugang:	Volltext
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