Trimethylsilyl Halide-Promoted Michaelis-Arbuzov Rearrangement

Trimethylsilyl Halide-Promoted Michaelis-Arbuzov Rearrangement

We describe a new, straightforward, and easy-to-handle method for achieving an unprecedented trimethylsilyl halide-catalyzed Michaelis−Arbuzov-like rearrangement. This rearrangement occurs at temperatures from room temperature to 80 °C and does not require addition of any alkyl halide. The scope and...

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Veröffentlicht in:Organic letters 2003-05, Vol.5 (10), p.1661-1664
Hauptverfasser: Renard, Pierre-Yves, Vayron, Philippe, Mioskowski, Charles
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container_title Organic letters
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creator Renard, Pierre-Yves
Vayron, Philippe
Mioskowski, Charles
description We describe a new, straightforward, and easy-to-handle method for achieving an unprecedented trimethylsilyl halide-catalyzed Michaelis−Arbuzov-like rearrangement. This rearrangement occurs at temperatures from room temperature to 80 °C and does not require addition of any alkyl halide. The scope and limitations of this new reaction are explored, as well as its mechanism.
doi_str_mv 10.1021/ol0342913
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title Trimethylsilyl Halide-Promoted Michaelis-Arbuzov Rearrangement
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