2-Nitroso-1,3-diphenyl-1,2,3,4-tetrahydrobenzo[b][1,6]naphthyridine

The title compound, C24H19N3O, crystallizes in the centrosymmetric space group P21/a with one mol­ecule in the asymmetric unit. The tetra­hydro­pyridine ring has a boat conformation. The dihedral angle between the fused pyridine rings is 16.2 (1)°. The equatorial and axial orientations of the two ph...

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Veröffentlicht in:Acta crystallographica. Section C, Crystal structure communications Crystal structure communications, 2003-03, Vol.59 (3), p.o153-o155
Hauptverfasser: Sivakumar, B., SethuSankar, K., Senthil Kumar, U. P., Jeyaraman, R., Velmurugan, D.
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Sprache:eng
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Zusammenfassung:The title compound, C24H19N3O, crystallizes in the centrosymmetric space group P21/a with one mol­ecule in the asymmetric unit. The tetra­hydro­pyridine ring has a boat conformation. The dihedral angle between the fused pyridine rings is 16.2 (1)°. The equatorial and axial orientations of the two phenyl groups with respect to the tetra­hydro­pyridine ring are confirmed. The nitroso group is coplanar with the attached C—N—C group. The interplanar angle formed between the fused tetra­hydro­pyridine and benzene planes is 13.4 (1)°. The crystal packing is stabilized by an intermolecular C—H⃛O hydrogen bond, which forms a C(9) graph‐set chain running along the [001] direction.
ISSN:0108-2701
1600-5759
DOI:10.1107/S0108270102022758