High-Pressure Raman Spectroscopic Study of the Ammonia−Borane Complex. Evidence for the Dihydrogen Bond
The Raman spectra of the ammonia−borane complex, NH3BH3, have been investigated as a function of pressure up to 40 kbar. Vibrational modes involving the NH3 group show negative pressure dependences, supporting the existence of the dihydrogen bond, but the vibrations of the BH3 group have a positive...
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| Veröffentlicht in: | Inorganic chemistry 2003-04, Vol.42 (8), p.2814-2816 |
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| Hauptverfasser: | , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
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