Formation, Preservation, and Cleavage of the Disulfide Bond by Vanadium

Reaction of the disulfide {HpicanS}2 (HpicanS is the carboxamide based on picolinate (pic) and o‐mercaptoaniline (anS); the {} brackets are used to denote disulfides) with [VOCl2(thf)2] leads to reductive scission of the disulfide bond and formation of the mixed‐valence (VIV/VV) complex anion [(OVpi...

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Veröffentlicht in:	Chemistry : a European journal 2003-04, Vol.9 (8), p.1805-1813
Hauptverfasser:	Wang, Dongren, Behrens, Axel, Farahbakhsh, Mahin, Gätjens, Jessica, Rehder, Dieter
Format:	Artikel
Sprache:	eng
Schlagworte:	amides biomimetic synthesis Crystallography, X-Ray disulfides Disulfides - chemistry Molecular Structure Organometallic Compounds - chemistry S ligands vanadium Vanadium - chemistry
Online-Zugang:	Volltext
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