α,2-, α,3-, and α,4-Dehydrophenol Radical Anions:  Formation, Reactivity, and Energetics Leading to the Heats of Formation of α,2-, α,3-, and α,4-Oxocyclohexadienylidene

We have regiospecifically generated the α,2-, α,3-, and α,4-dehydrophenoxide anions by collisional activation of o-, m-, and p-nitrobenzoate. The α,2 and α,4 isomers also were synthesized by reacting o-benzyne radical anion with carbon dioxide and electron ionization of p-diazophenol. All three dehy...

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Veröffentlicht in:	Journal of the American Chemical Society 2003-04, Vol.125 (15), p.4643-4651
Hauptverfasser:	Reed, Dana R, Hare, Michael C, Fattahi, Alireza, Chung, Gyusung, Gordon, Mark S, Kass, Steven R
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemistry Exact sciences and technology Free radicals chemistry Organic chemistry Reactivity and mechanisms
Online-Zugang:	Volltext
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