Vanadium Haloperoxidase-Catalyzed Bromination and Cyclization of Terpenes

Marine red algae (Rhodophyta) are a rich source of bioactive halogenated natural products, including cyclic terpenes. The biogenesis of certain cyclic halogenated marine natural products is thought to involve marine haloperoxidase enzymes. Evidence is presented that vanadium bromoperoxidase (V−BrPO)...

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Veröffentlicht in:	Journal of the American Chemical Society 2003-04, Vol.125 (13), p.3688-3689
Hauptverfasser:	Carter-Franklin, Jayme N, Parrish, Jon D, Tschirret-Guth, Richard A, Little, R. Daniel, Butler, Alison
Format:	Artikel
Sprache:	eng
Schlagworte:	Biological and medical sciences Catalysis Chemistry Cyclization Exact sciences and technology Fundamental and applied biological sciences. Psychology Hydrocarbons, Brominated - chemical synthesis Hydrocarbons, Brominated - metabolism Kinetics and mechanisms Mechanisms. Catalysis. Electron transfer. Models Molecular biophysics Organic chemistry Peroxidases - chemistry Peroxidases - metabolism Physical chemistry in biology Reactivity and mechanisms Rhodophyta - enzymology Terpenes - chemical synthesis Terpenes - chemistry Terpenes - metabolism
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