Fe(II) and Fe(III) Mononuclear Complexes with a Pentadentate Ligand Built on the 1,3-Diaminopropane Unit. Structures and Spectroscopic and Electrochemical Properties. Reaction with H2O2
Two new iron complexes, [L5 3FeIICl]PF6 (1·PF6) and [(L5 3H+)FeIIICl3]PF6 (2·PF6), were synthesized (L5 3 = N-methyl-N,N‘,N‘-tris(2-pyridylmethyl)propane-1,3-diamine), and their molecular structures were determined by X-ray crystallography. Their behavior in solution was studied by UV−vis spectrosco...
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Veröffentlicht in: | Inorganic chemistry 2003-04, Vol.42 (7), p.2470-2477 |
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Hauptverfasser: | , , , , , , , |
Format: | Artikel |
Sprache: | eng |
Online-Zugang: | Volltext |
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