Fe(II) and Fe(III) Mononuclear Complexes with a Pentadentate Ligand Built on the 1,3-Diaminopropane Unit. Structures and Spectroscopic and Electrochemical Properties. Reaction with H2O2

Two new iron complexes, [L5 3FeIICl]PF6 (1·PF6) and [(L5 3H+)FeIIICl3]PF6 (2·PF6), were synthesized (L5 3 = N-methyl-N,N‘,N‘-tris(2-pyridylmethyl)propane-1,3-diamine), and their molecular structures were determined by X-ray crystallography. Their behavior in solution was studied by UV−vis spectrosco...

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Veröffentlicht in:Inorganic chemistry 2003-04, Vol.42 (7), p.2470-2477
Hauptverfasser: Balland, Véronique, Banse, Frédéric, Anxolabéhère-Mallart, Elodie, Ghiladi, Morten, Mattioli, Tony A, Philouze, Christian, Blondin, Geneviève, Girerd, Jean-Jacques
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Sprache:eng
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