The nature of the colloidal 'glass' transition

The dynamically arrested state of matter is discussed in the context of athermal systems, such as the hard sphere colloidal arrest. We believe that the singular dynamical behaviour near arrest expressed, for example, in how the diffusion constant vanishes may be 'universal', in a sense to...

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Veröffentlicht in:Faraday discussions 2003-01, Vol.123, p.13-26
Hauptverfasser: Dawson, Kenneth A, Lawlor, A, DeGregorio, Paolo, McCullagh, Gavin D, Zaccarelli, Emanuela, Foffi, Giuseppe, Tartaglia, Piero
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container_issue
container_start_page 13
container_title Faraday discussions
container_volume 123
creator Dawson, Kenneth A
Lawlor, A
DeGregorio, Paolo
McCullagh, Gavin D
Zaccarelli, Emanuela
Foffi, Giuseppe
Tartaglia, Piero
description The dynamically arrested state of matter is discussed in the context of athermal systems, such as the hard sphere colloidal arrest. We believe that the singular dynamical behaviour near arrest expressed, for example, in how the diffusion constant vanishes may be 'universal', in a sense to be discussed in the paper. Based on this we argue the merits of studying the problem with simple lattice models. This, by analogy with the the critical point of the Ising model, should lead us to clarify the questions, and begin the program of establishing the degree of universality to be expected. We deal only with 'ideal' athermal dynamical arrest transitions, such as those found for hard sphere systems. However, it is argued that dynamically available volume (DAV) is the relevant order parameter of the transition, and that universal mechanisms may be well expressed in terms of DAV. For simple lattice models we give examples of simple laws that emerge near the dynamical arrest, emphasising the idea of a near-ideal gas of 'holes', interacting to give the power law diffusion constant scaling near the arrest. We also seek to open the discussion of the possibility of an underlying weak coupling theory of the dynamical arrest transition, based on DAV.
doi_str_mv 10.1039/b204624e
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title The nature of the colloidal 'glass' transition
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