Adatom kinetics on and below the surface: the existence of a new diffusion channel
Employing density-functional theory in combination with scanning tunneling microscopy, we demonstrate that a thin metallic film on a semiconductor surface may open an efficient and hitherto not expected diffusion channel for lateral adatom transport: adatoms may prefer diffusion within this metallic...
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Veröffentlicht in: | Physical review letters 2003-02, Vol.90 (5), p.056101-056101, Article 056101 |
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creator | Neugebauer, Jörg Zywietz, Tosja K Scheffler, Matthias Northrup, John E Chen, Huajie Feenstra, R M |
description | Employing density-functional theory in combination with scanning tunneling microscopy, we demonstrate that a thin metallic film on a semiconductor surface may open an efficient and hitherto not expected diffusion channel for lateral adatom transport: adatoms may prefer diffusion within this metallic layer rather than on top of the surface. Based on this concept, we interpret recent experiments: We explain why and when In acts as a surfactant on GaN surfaces, why Ga acts as an autosurfactant, and how this mechanism can be used to optimize group-III nitride growth. |
doi_str_mv | 10.1103/physrevlett.90.056101 |
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title | Adatom kinetics on and below the surface: the existence of a new diffusion channel |
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