Synthesis, Structure, and Magnetic Properties of Two New Vanadocarboxylates with Three-Dimensional Hybrid Frameworks

(VIII(OH))2{C6H2(CO2)4}·4H2O (labeled MIL-60) and VIII(OH){2(O2C)C6H2(COOH)2}·H2O (labeled MIL-61) were hydrothermally synthesized from mixtures of VCl3, 1,2,4,5-benzenetetracarboxylic acid, and water heated for 3 days at 473 K. The structure of MIL-60 was solved from single-crystal X-ray diffractio...

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Veröffentlicht in:Inorganic chemistry 2003-03, Vol.42 (5), p.1739-1743
Hauptverfasser: Barthelet, K, Riou, D, Nogues, M, Férey, G
Format: Artikel
Sprache:eng
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