Synthesis, Structure, and Magnetic Properties of Two New Vanadocarboxylates with Three-Dimensional Hybrid Frameworks
(VIII(OH))2{C6H2(CO2)4}·4H2O (labeled MIL-60) and VIII(OH){2(O2C)C6H2(COOH)2}·H2O (labeled MIL-61) were hydrothermally synthesized from mixtures of VCl3, 1,2,4,5-benzenetetracarboxylic acid, and water heated for 3 days at 473 K. The structure of MIL-60 was solved from single-crystal X-ray diffractio...
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Veröffentlicht in: | Inorganic chemistry 2003-03, Vol.42 (5), p.1739-1743 |
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Hauptverfasser: | , , , |
Format: | Artikel |
Sprache: | eng |
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