Electron and Hydrogen-Atom Self-Exchange Reactions of Iron and Cobalt Coordination Complexes

Reported here are self-exchange reactions between iron 2,2‘-bi(tetrahydro)pyrimidine (H2bip) complexes and between cobalt 2,2‘-biimidazoline (H2bim) complexes. The 1H NMR resonances of [FeII(H2bip)3]2+ are broadened upon addition of [FeIII(H2bip)3]3+, indicating that electron self-exchange occurs wi...

Ausführliche Beschreibung