Chiral Stimuli-Responsive Gels:  Helicity Induction in Poly(phenylacetylene) Gels Bearing a Carboxyl Group with Chiral Amines

Poly(phenylacetylene) gels (gel-1-H and gel-2-H) bearing a carboxy pendant were synthesized either by the copolymerization of (4-carboxyphenyl)acetylene (gel-1-H) with a bis(phenylacetylene) derivative as the cross-linking reagent using a rhodium complex ([Rh(cod)2]BF4:  cod = 1,5-cyclooctadiene) as...

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Veröffentlicht in:	Journal of the American Chemical Society 2003-03, Vol.125 (9), p.2516-2523
Hauptverfasser:	Goto, Hidetoshi, Zhang, Hao Qian, Yashima, Eiji
Format:	Artikel
Sprache:	eng
Schlagworte:	Applied sciences Exact sciences and technology Organic polymers Physicochemistry of polymers Properties and characterization Solution and gel properties
Online-Zugang:	Volltext
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