Barium azacryptand sodide, the first alkalide with an alkaline Earth cation, also contains a novel dimer, (Na(2))(2-)

Barium azacryptand sodide, the first alkalide with an alkaline Earth cation, also contains a novel dimer, (Na(2))(2-)

The first barium sodide, with stoichiometry Ba(2+)(H(5)Azacryptand[2.2.2](-))Na(-).2MeNH(2), was synthesized by the reaction of Ba, Na, and H(6)Azacryptand[2.2.2] in NH(3)-MeNH(2) solution. It was characterized by X-ray crystallography, (23)Na MAS NMR, hydrogen evolution, DSC, optical spectroscopy,...

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Veröffentlicht in:Journal of the American Chemical Society 2003-02, Vol.125 (8), p.2259-2263
Hauptverfasser: Redko, Mikhail Y, Huang, Rui H, Jackson, James E, Harrison, James F, Dye, James L
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creator Redko, Mikhail Y
Huang, Rui H
Jackson, James E
Harrison, James F
Dye, James L
description The first barium sodide, with stoichiometry Ba(2+)(H(5)Azacryptand[2.2.2](-))Na(-).2MeNH(2), was synthesized by the reaction of Ba, Na, and H(6)Azacryptand[2.2.2] in NH(3)-MeNH(2) solution. It was characterized by X-ray crystallography, (23)Na MAS NMR, hydrogen evolution, DSC, optical spectroscopy, and magnetic susceptibility. This is the first sodide in which the sodium anions form (Na(2))(2)(-) dimers. Previous theoretical predictions were verified by a calculation of the potential energy curve for the dimer in the field of the surrounding charges, whose positions were determined from the crystal structure.
doi_str_mv 10.1021/ja027241m
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title Barium azacryptand sodide, the first alkalide with an alkaline Earth cation, also contains a novel dimer, (Na(2))(2-)
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