Vesicles and Polymerized Vesicles from Thiophene-Containing Rod-Coil Block Copolymers

Spontaneous formation of vesicles in both organic solvents and water is observed for new rod–coil‐type diblock copolymers containing thiophene groups. The thiophene groups located in the skin of the aggregates can couple to give polymerized vesicles (see picture and cover picture). The vesicles are...

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Veröffentlicht in:Angewandte Chemie International Edition 2003-02, Vol.42 (7), p.772-776
Hauptverfasser: Vriezema, Dennis M., Hoogboom, Johan, Velonia, Kelly, Takazawa, Ken, Christianen, Peter C. M., Maan, Jan. C., Rowan, Alan E., Nolte, Roeland J. M.
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container_end_page 776
container_issue 7
container_start_page 772
container_title Angewandte Chemie International Edition
container_volume 42
creator Vriezema, Dennis M.
Hoogboom, Johan
Velonia, Kelly
Takazawa, Ken
Christianen, Peter C. M.
Maan, Jan. C.
Rowan, Alan E.
Nolte, Roeland J. M.
description Spontaneous formation of vesicles in both organic solvents and water is observed for new rod–coil‐type diblock copolymers containing thiophene groups. The thiophene groups located in the skin of the aggregates can couple to give polymerized vesicles (see picture and cover picture). The vesicles are capable of including enzymes, which results in catalytically active microreactors that are permeable to substrate molecules.
doi_str_mv 10.1002/anie.200390204
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source MEDLINE; Wiley Online Library Journals Frontfile Complete
subjects Amino Acids - chemistry
block copolymers
Candida - enzymology
enzymes
Fungal Proteins
Lipase - metabolism
Microscopy, Electron
polyisocyanides
Polymers - chemistry
Thiophenes - chemistry
vesicles
title Vesicles and Polymerized Vesicles from Thiophene-Containing Rod-Coil Block Copolymers
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