Vesicles and Polymerized Vesicles from Thiophene-Containing Rod-Coil Block Copolymers
Spontaneous formation of vesicles in both organic solvents and water is observed for new rod–coil‐type diblock copolymers containing thiophene groups. The thiophene groups located in the skin of the aggregates can couple to give polymerized vesicles (see picture and cover picture). The vesicles are...
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Veröffentlicht in: | Angewandte Chemie International Edition 2003-02, Vol.42 (7), p.772-776 |
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container_title | Angewandte Chemie International Edition |
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creator | Vriezema, Dennis M. Hoogboom, Johan Velonia, Kelly Takazawa, Ken Christianen, Peter C. M. Maan, Jan. C. Rowan, Alan E. Nolte, Roeland J. M. |
description | Spontaneous formation of vesicles in both organic solvents and water is observed for new rod–coil‐type diblock copolymers containing thiophene groups. The thiophene groups located in the skin of the aggregates can couple to give polymerized vesicles (see picture and cover picture). The vesicles are capable of including enzymes, which results in catalytically active microreactors that are permeable to substrate molecules. |
doi_str_mv | 10.1002/anie.200390204 |
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The vesicles are capable of including enzymes, which results in catalytically active microreactors that are permeable to substrate molecules.</description><subject>Amino Acids - chemistry</subject><subject>block copolymers</subject><subject>Candida - enzymology</subject><subject>enzymes</subject><subject>Fungal Proteins</subject><subject>Lipase - metabolism</subject><subject>Microscopy, Electron</subject><subject>polyisocyanides</subject><subject>Polymers - chemistry</subject><subject>Thiophenes - chemistry</subject><subject>vesicles</subject><issn>1433-7851</issn><issn>1521-3773</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2003</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNqFkD1PwzAQhi0E4ntlRJnYUmxfbMcjVKUgIb4po-UkFzAkcYlbQfn1BKUqbEznk5_30ekl5IDRAaOUH9vG4YBTCppymqyRbSY4i0EpWO_eCUCsUsG2yE4Irx2fplRuki3GhZZMy23yOMHg8gpDZJsiuvHVosbWfWERrT7K1tfRw4vz0xdsMB76ZmZd45rn6M4X3eqq6LTy-Vs09NM-H_bIRmmrgPvLuUsez0YPw_P48np8MTy5jHNQOokLRbnIumMlTShNeVFmAqRSFFKaC80zbaW0NhGQAMsVJjoDLSSyMisYWA275Kj3Tlv_PscwM7ULOVaVbdDPg1FAuRYaOnDQg3nrQ2ixNNPW1bZdGEbNT5Hmp0izKrILHC7N86zG4hdfNtcBugc-XIWLf3Tm5Opi9Fce91kXZvi5ytr2zUgFSpinq7ERk_sJu5UTM4Zvvo6N0A</recordid><startdate>20030217</startdate><enddate>20030217</enddate><creator>Vriezema, Dennis M.</creator><creator>Hoogboom, Johan</creator><creator>Velonia, Kelly</creator><creator>Takazawa, Ken</creator><creator>Christianen, Peter C. 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source | MEDLINE; Wiley Online Library Journals Frontfile Complete |
subjects | Amino Acids - chemistry block copolymers Candida - enzymology enzymes Fungal Proteins Lipase - metabolism Microscopy, Electron polyisocyanides Polymers - chemistry Thiophenes - chemistry vesicles |
title | Vesicles and Polymerized Vesicles from Thiophene-Containing Rod-Coil Block Copolymers |
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