The Solid State Structure of [B10H11]- and Its Dynamic NMR Spectra in Solution

The structure of [PPh3(benzyl)][B10H11] was determined at −123 °C and 24 °C by single-crystal X-ray analyses. The B10 core of [B10H11]- is similar in shape to that of [B10H10]2-. The 11th H atom asymmetrically caps a polar face of the cluster and shows no tendency for disorder in the solid state. Va...

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Veröffentlicht in:	Inorganic chemistry 2003-02, Vol.42 (4), p.1175-1186
Hauptverfasser:	Shore, Sheldon G, Hamilton, Ewan J. M, Bridges, Adam N, Bausch, Joseph, Krause-Bauer, Jeanette A, Dou, Danan, Liu, Jianping, Liu, Shengming, Du, Bin, Hall, Heather, Meyers, Edward A, Vermillion, Karl E
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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