The Addition Polymerization of a PC Bond: A Route to New Phosphine Polymers
Addition polymerization, the most general method of preparation for organic polymers, has successfully been extended to PC bonds. The polymerization of a phosphaalkene has been initiated by thermolysis or with alkyllithium reagents. The unprecedented poly(methylenephosphine)s are easily oxidized us...
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| Veröffentlicht in: | Journal of the American Chemical Society 2003-02, Vol.125 (6), p.1480-1481 |
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| container_end_page | 1481 |
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| container_issue | 6 |
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| container_title | Journal of the American Chemical Society |
| container_volume | 125 |
| creator | Tsang, Chi-Wing Yam, Mandy Gates, Derek P. |
| description | Addition polymerization, the most general method of preparation for organic polymers, has successfully been extended to PC bonds. The polymerization of a phosphaalkene has been initiated by thermolysis or with alkyllithium reagents. The unprecedented poly(methylenephosphine)s are easily oxidized using oxygen or sulfur to give air stable macromolecules. A molecular weight (M w) of 35000 g/mol for the poly(methylenephosphine sulfude) was estimated by light-scattering GPC. |
| doi_str_mv | 10.1021/ja029120s |
| format | Article |
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The polymerization of a phosphaalkene has been initiated by thermolysis or with alkyllithium reagents. The unprecedented poly(methylenephosphine)s are easily oxidized using oxygen or sulfur to give air stable macromolecules. A molecular weight (M w) of 35000 g/mol for the poly(methylenephosphine sulfude) was estimated by light-scattering GPC.</description><identifier>ISSN: 0002-7863</identifier><identifier>EISSN: 1520-5126</identifier><identifier>DOI: 10.1021/ja029120s</identifier><identifier>PMID: 12568599</identifier><identifier>CODEN: JACSAT</identifier><language>eng</language><publisher>Washington, DC: American Chemical Society</publisher><subject>Applied sciences ; Exact sciences and technology ; Organic polymers ; Physicochemistry of polymers ; Polymerization ; Preparation, kinetics, thermodynamics, mechanism and catalysts</subject><ispartof>Journal of the American Chemical Society, 2003-02, Vol.125 (6), p.1480-1481</ispartof><rights>Copyright © 2003 American Chemical Society</rights><rights>2003 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://pubs.acs.org/doi/pdf/10.1021/ja029120s$$EPDF$$P50$$Gacs$$H</linktopdf><linktohtml>$$Uhttps://pubs.acs.org/doi/10.1021/ja029120s$$EHTML$$P50$$Gacs$$H</linktohtml><link.rule.ids>314,776,780,27053,27901,27902,56713,56763</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=14526591$$DView record in Pascal Francis$$Hfree_for_read</backlink><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/12568599$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Tsang, Chi-Wing</creatorcontrib><creatorcontrib>Yam, Mandy</creatorcontrib><creatorcontrib>Gates, Derek P.</creatorcontrib><title>The Addition Polymerization of a PC Bond: A Route to New Phosphine Polymers</title><title>Journal of the American Chemical Society</title><addtitle>J. Am. Chem. Soc</addtitle><description>Addition polymerization, the most general method of preparation for organic polymers, has successfully been extended to PC bonds. The polymerization of a phosphaalkene has been initiated by thermolysis or with alkyllithium reagents. The unprecedented poly(methylenephosphine)s are easily oxidized using oxygen or sulfur to give air stable macromolecules. 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| language | eng |
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| source | ACS Publications |
| subjects | Applied sciences Exact sciences and technology Organic polymers Physicochemistry of polymers Polymerization Preparation, kinetics, thermodynamics, mechanism and catalysts |
| title | The Addition Polymerization of a PC Bond: A Route to New Phosphine Polymers |
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