Controlled Formation of Highly Ordered Cubic and Hexagonal Mesoporous Nanocrystalline Yttria-Zirconia and Ceria-Zirconia Thin Films Exhibiting High Thermal Stability

Yttria–zirconia and ceria–zirconia mesoporous thin films adopt either a cubic or 2D hexagonal mesostructure (see picture) depending on the quantity of water employed during the post‐processing of the films. The hexagonal films are thermally stable above 400 °C, while the cubic forms retain their int...

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Veröffentlicht in:	Angewandte Chemie International Edition 2003-01, Vol.42 (3), p.347-351
Hauptverfasser:	Crepaldi, Eduardo L., de A. A. Soler-Illia, Galo J., Bouchara, Anne, Grosso, David, Durand, Dominique, Sanchez, Clément
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Sprache:	eng
Schlagworte:	cerium mesoporous materials thin films yttrium zirconium
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creator	Crepaldi, Eduardo L. de A. A. Soler-Illia, Galo J. Bouchara, Anne Grosso, David Durand, Dominique Sanchez, Clément
description	Yttria–zirconia and ceria–zirconia mesoporous thin films adopt either a cubic or 2D hexagonal mesostructure (see picture) depending on the quantity of water employed during the post‐processing of the films. The hexagonal films are thermally stable above 400 °C, while the cubic forms retain their integrity up to 700 °C; both forms continue to be porous at temperatures as high as 800 °C. Such robust and easily prepared crystalline materials may have many useful applications, for example, in the design of sensors, electrode materials, and catalysts.
doi_str_mv	10.1002/anie.200390113
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The hexagonal films are thermally stable above 400 °C, while the cubic forms retain their integrity up to 700 °C; both forms continue to be porous at temperatures as high as 800 °C. Such robust and easily prepared crystalline materials may have many useful applications, for example, in the design of sensors, electrode materials, and catalysts.</abstract><cop>Weinheim</cop><pub>WILEY-VCH Verlag</pub><pmid>12548696</pmid><doi>10.1002/anie.200390113</doi><tpages>5</tpages><oa>free_for_read</oa></addata></record>
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subjects	cerium mesoporous materials thin films yttrium zirconium
title	Controlled Formation of Highly Ordered Cubic and Hexagonal Mesoporous Nanocrystalline Yttria-Zirconia and Ceria-Zirconia Thin Films Exhibiting High Thermal Stability
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