The Stabilisation of Monomeric Parent Compounds of Phosphanyl- and Arsanylboranes

The structures of the parent compounds of phosphanyl‐ and arsanylboranes, H2BPH2 and H2BAsH2, were calculated by DFT‐B3LYP methods. Such compounds have not previously been obtained preparatively. By applying the concept of Lewis acid/base stabilisation, [(CO)5W(H2EBH2⋅NMe3)] (E=P (3), As (4)) deriva...

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Veröffentlicht in:	Chemistry : a European journal 2003-01, Vol.9 (2), p.515-519
Hauptverfasser:	Vogel, Ulf, Hoemensch, Petra, Schwan, Karl-Christian, Timoshkin, Alexey Y., Scheer, Manfred
Format:	Artikel
Sprache:	eng
Schlagworte:	arsenic boron density functional calculations phosphorus tungsten
Online-Zugang:	Volltext
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