Attaching Perylene Dyes to Polyfluorene:  Three Simple, Efficient Methods for Facile Color Tuning of Light-Emitting Polymers

The emission color of fluorene-based polymers can be facilely tuned across the whole visible spectrum by copolymerization with perylene dyes. Methods are demonstrated for incorporation of the dyes in the polymer mainchain, at the chain termini, or as side chains. Efficient energy transfer causes the...

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Veröffentlicht in:Journal of the American Chemical Society 2003-01, Vol.125 (2), p.437-443
Hauptverfasser: Ego, Christophe, Marsitzky, Dirk, Becker, Stefan, Zhang, Jingying, Grimsdale, Andrew C, Müllen, Klaus, MacKenzie, J. Devin, Silva, Carlos, Friend, Richard H
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container_end_page 443
container_issue 2
container_start_page 437
container_title Journal of the American Chemical Society
container_volume 125
creator Ego, Christophe
Marsitzky, Dirk
Becker, Stefan
Zhang, Jingying
Grimsdale, Andrew C
Müllen, Klaus
MacKenzie, J. Devin
Silva, Carlos
Friend, Richard H
description The emission color of fluorene-based polymers can be facilely tuned across the whole visible spectrum by copolymerization with perylene dyes. Methods are demonstrated for incorporation of the dyes in the polymer mainchain, at the chain termini, or as side chains. Efficient energy transfer causes the emission to come solely from the dye units. Efficient LEDs have been made from the copolymers with dyes in the mainchain.
doi_str_mv 10.1021/ja0205784
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source American Chemical Society Journals
subjects Applied sciences
Chemical modifications
Chemical reactions and properties
Exact sciences and technology
Organic polymers
Physicochemistry of polymers
title Attaching Perylene Dyes to Polyfluorene:  Three Simple, Efficient Methods for Facile Color Tuning of Light-Emitting Polymers
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