Attaching Perylene Dyes to Polyfluorene: Three Simple, Efficient Methods for Facile Color Tuning of Light-Emitting Polymers
The emission color of fluorene-based polymers can be facilely tuned across the whole visible spectrum by copolymerization with perylene dyes. Methods are demonstrated for incorporation of the dyes in the polymer mainchain, at the chain termini, or as side chains. Efficient energy transfer causes the...
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Veröffentlicht in: | Journal of the American Chemical Society 2003-01, Vol.125 (2), p.437-443 |
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container_title | Journal of the American Chemical Society |
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creator | Ego, Christophe Marsitzky, Dirk Becker, Stefan Zhang, Jingying Grimsdale, Andrew C Müllen, Klaus MacKenzie, J. Devin Silva, Carlos Friend, Richard H |
description | The emission color of fluorene-based polymers can be facilely tuned across the whole visible spectrum by copolymerization with perylene dyes. Methods are demonstrated for incorporation of the dyes in the polymer mainchain, at the chain termini, or as side chains. Efficient energy transfer causes the emission to come solely from the dye units. Efficient LEDs have been made from the copolymers with dyes in the mainchain. |
doi_str_mv | 10.1021/ja0205784 |
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subjects | Applied sciences Chemical modifications Chemical reactions and properties Exact sciences and technology Organic polymers Physicochemistry of polymers |
title | Attaching Perylene Dyes to Polyfluorene: Three Simple, Efficient Methods for Facile Color Tuning of Light-Emitting Polymers |
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