Attaching Perylene Dyes to Polyfluorene:  Three Simple, Efficient Methods for Facile Color Tuning of Light-Emitting Polymers

The emission color of fluorene-based polymers can be facilely tuned across the whole visible spectrum by copolymerization with perylene dyes. Methods are demonstrated for incorporation of the dyes in the polymer mainchain, at the chain termini, or as side chains. Efficient energy transfer causes the...

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Veröffentlicht in:Journal of the American Chemical Society 2003-01, Vol.125 (2), p.437-443
Hauptverfasser: Ego, Christophe, Marsitzky, Dirk, Becker, Stefan, Zhang, Jingying, Grimsdale, Andrew C, Müllen, Klaus, MacKenzie, J. Devin, Silva, Carlos, Friend, Richard H
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Sprache:eng
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Zusammenfassung:The emission color of fluorene-based polymers can be facilely tuned across the whole visible spectrum by copolymerization with perylene dyes. Methods are demonstrated for incorporation of the dyes in the polymer mainchain, at the chain termini, or as side chains. Efficient energy transfer causes the emission to come solely from the dye units. Efficient LEDs have been made from the copolymers with dyes in the mainchain.
ISSN:0002-7863
1520-5126
DOI:10.1021/ja0205784