The Adsorption of Cyclopropane and Cyclohexane on Cu(111): An Experimental and Theoretical Investigation on the Nature of the CH−Metal Interaction

On contact with transition metals, saturated hydrocarbons reveal pronounced red shifts in the C−H stretching region in their IR spectra (shaded region in picture), which are discussed in connection with C−H activation. Detailed ab initio calculations for cyclopropane and cyclohexane on a Cu surface...

Ausführliche Beschreibung

Gespeichert in:

Bibliographische Detailangaben
Veröffentlicht in:	Angewandte Chemie International Edition 2002-05, Vol.41 (10), p.1735-1737
Hauptverfasser:	Fosser, Kari A., Nuzzo, Ralph G., Bagus, Paul S., Wöll, Christof
Format:	Artikel
Sprache:	eng
Schlagworte:	ab initio calculations adsorption alkanes IR spectroscopy surface chemistry
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!

container_end_page	1737
container_issue	10
container_start_page	1735
container_title	Angewandte Chemie International Edition
container_volume	41
creator	Fosser, Kari A. Nuzzo, Ralph G. Bagus, Paul S. Wöll, Christof
description	On contact with transition metals, saturated hydrocarbons reveal pronounced red shifts in the C−H stretching region in their IR spectra (shaded region in picture), which are discussed in connection with C−H activation. Detailed ab initio calculations for cyclopropane and cyclohexane on a Cu surface suggest that this anomaly is caused by an unexpected chemical interaction.
doi_str_mv	10.1002/1521-3773(20020517)41:10<1735::AID-ANIE1735>3.0.CO;2-G
format	Article
fullrecord	<record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_72932991</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>72932991</sourcerecordid><originalsourceid>FETCH-LOGICAL-c4745-43724b42c60aa40afc3961ad3d724d13cde978d06a14b152b231d3a5c1da2a3b3</originalsourceid><addsrcrecordid>eNqVkcFy0zAQhj0MDC2FV2B8YtqDg1aSrTgwnTFu6mamJJcABw47iqVQg2MbyYbkDTgzPCFPghyn4cSBk_yvf32r3d_zLoGMgBD6EkIKAROCnVMnSQjigsMEyGsQLJxMktlVkMxn015dshEZpYtXNMgeeKfHiw_dN2csEOMQTrwn1n52oPGYRI-9E4hFSKI4PvV-Le-0nyhbm6Yt6sqv1366y8u6MXUjK-3LSg2FO73ttbOk3TkAXEz8pPKn20abYqOrVpZ7r8PVRrdF7vSs-qZtW3ySA7nyW9drLtvO6L5Pr9Kb3z9-vtXt3t1qI_Pe-9R7tJal1c8O55n37nq6TG-C20U2S5PbIOeChwFngvIVp3lEpORErnMWRyAVU66ugOVKx2KsSCSBr9xeVpSBYjLMQUkq2YqdeS8Grpv2a-feipvC5ros3aR1Z1HQmNE4Bmd8PxhzU1tr9BobN7U0OwSCfV7Yrx37teN9Xshh_9clhOjywvu8kCHBdIEUMwd-fnhBt9po9Rd7CMgZPg6G70Wpd__Z9h9djzVHDwZ6YVu9PdKl-YKRYCLED_MM3_D0arnMrpGzP9jawG0</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>72932991</pqid></control><display><type>article</type><title>The Adsorption of Cyclopropane and Cyclohexane on Cu(111): An Experimental and Theoretical Investigation on the Nature of the CH−Metal Interaction</title><source>Wiley Online Library Journals Frontfile Complete</source><creator>Fosser, Kari A. ; Nuzzo, Ralph G. ; Bagus, Paul S. ; Wöll, Christof</creator><creatorcontrib>Fosser, Kari A. ; Nuzzo, Ralph G. ; Bagus, Paul S. ; Wöll, Christof</creatorcontrib><description>On contact with transition metals, saturated hydrocarbons reveal pronounced red shifts in the C−H stretching region in their IR spectra (shaded region in picture), which are discussed in connection with C−H activation. Detailed ab initio calculations for cyclopropane and cyclohexane on a Cu surface suggest that this anomaly is caused by an unexpected chemical interaction.</description><identifier>ISSN: 1433-7851</identifier><identifier>EISSN: 1521-3773</identifier><identifier>DOI: 10.1002/1521-3773(20020517)41:10<1735::AID-ANIE1735>3.0.CO;2-G</identifier><identifier>PMID: 19750699</identifier><language>eng</language><publisher>Weinheim: WILEY-VCH Verlag GmbH</publisher><subject>ab initio calculations ; adsorption ; alkanes ; IR spectroscopy ; surface chemistry</subject><ispartof>Angewandte Chemie International Edition, 2002-05, Vol.41 (10), p.1735-1737</ispartof><rights>2002 WILEY‐VCH Verlag GmbH, Weinheim, Fed. Rep. of Germany</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c4745-43724b42c60aa40afc3961ad3d724d13cde978d06a14b152b231d3a5c1da2a3b3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2F1521-3773%2820020517%2941%3A10%3C1735%3A%3AAID-ANIE1735%3E3.0.CO%3B2-G$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2F1521-3773%2820020517%2941%3A10%3C1735%3A%3AAID-ANIE1735%3E3.0.CO%3B2-G$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,777,781,1412,27905,27906,45555,45556</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/19750699$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Fosser, Kari A.</creatorcontrib><creatorcontrib>Nuzzo, Ralph G.</creatorcontrib><creatorcontrib>Bagus, Paul S.</creatorcontrib><creatorcontrib>Wöll, Christof</creatorcontrib><title>The Adsorption of Cyclopropane and Cyclohexane on Cu(111): An Experimental and Theoretical Investigation on the Nature of the CH−Metal Interaction</title><title>Angewandte Chemie International Edition</title><addtitle>Angew. Chem. Int. Ed</addtitle><description>On contact with transition metals, saturated hydrocarbons reveal pronounced red shifts in the C−H stretching region in their IR spectra (shaded region in picture), which are discussed in connection with C−H activation. Detailed ab initio calculations for cyclopropane and cyclohexane on a Cu surface suggest that this anomaly is caused by an unexpected chemical interaction.</description><subject>ab initio calculations</subject><subject>adsorption</subject><subject>alkanes</subject><subject>IR spectroscopy</subject><subject>surface chemistry</subject><issn>1433-7851</issn><issn>1521-3773</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2002</creationdate><recordtype>article</recordtype><recordid>eNqVkcFy0zAQhj0MDC2FV2B8YtqDg1aSrTgwnTFu6mamJJcABw47iqVQg2MbyYbkDTgzPCFPghyn4cSBk_yvf32r3d_zLoGMgBD6EkIKAROCnVMnSQjigsMEyGsQLJxMktlVkMxn015dshEZpYtXNMgeeKfHiw_dN2csEOMQTrwn1n52oPGYRI-9E4hFSKI4PvV-Le-0nyhbm6Yt6sqv1366y8u6MXUjK-3LSg2FO73ttbOk3TkAXEz8pPKn20abYqOrVpZ7r8PVRrdF7vSs-qZtW3ySA7nyW9drLtvO6L5Pr9Kb3z9-vtXt3t1qI_Pe-9R7tJal1c8O55n37nq6TG-C20U2S5PbIOeChwFngvIVp3lEpORErnMWRyAVU66ugOVKx2KsSCSBr9xeVpSBYjLMQUkq2YqdeS8Grpv2a-feipvC5ros3aR1Z1HQmNE4Bmd8PxhzU1tr9BobN7U0OwSCfV7Yrx37teN9Xshh_9clhOjywvu8kCHBdIEUMwd-fnhBt9po9Rd7CMgZPg6G70Wpd__Z9h9djzVHDwZ6YVu9PdKl-YKRYCLED_MM3_D0arnMrpGzP9jawG0</recordid><startdate>20020517</startdate><enddate>20020517</enddate><creator>Fosser, Kari A.</creator><creator>Nuzzo, Ralph G.</creator><creator>Bagus, Paul S.</creator><creator>Wöll, Christof</creator><general>WILEY-VCH Verlag GmbH</general><general>WILEY‐VCH Verlag GmbH</general><scope>BSCLL</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope></search><sort><creationdate>20020517</creationdate><title>The Adsorption of Cyclopropane and Cyclohexane on Cu(111): An Experimental and Theoretical Investigation on the Nature of the CH−Metal Interaction</title><author>Fosser, Kari A. ; Nuzzo, Ralph G. ; Bagus, Paul S. ; Wöll, Christof</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c4745-43724b42c60aa40afc3961ad3d724d13cde978d06a14b152b231d3a5c1da2a3b3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2002</creationdate><topic>ab initio calculations</topic><topic>adsorption</topic><topic>alkanes</topic><topic>IR spectroscopy</topic><topic>surface chemistry</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Fosser, Kari A.</creatorcontrib><creatorcontrib>Nuzzo, Ralph G.</creatorcontrib><creatorcontrib>Bagus, Paul S.</creatorcontrib><creatorcontrib>Wöll, Christof</creatorcontrib><collection>Istex</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><jtitle>Angewandte Chemie International Edition</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Fosser, Kari A.</au><au>Nuzzo, Ralph G.</au><au>Bagus, Paul S.</au><au>Wöll, Christof</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>The Adsorption of Cyclopropane and Cyclohexane on Cu(111): An Experimental and Theoretical Investigation on the Nature of the CH−Metal Interaction</atitle><jtitle>Angewandte Chemie International Edition</jtitle><addtitle>Angew. Chem. Int. Ed</addtitle><date>2002-05-17</date><risdate>2002</risdate><volume>41</volume><issue>10</issue><spage>1735</spage><epage>1737</epage><pages>1735-1737</pages><issn>1433-7851</issn><eissn>1521-3773</eissn><abstract>On contact with transition metals, saturated hydrocarbons reveal pronounced red shifts in the C−H stretching region in their IR spectra (shaded region in picture), which are discussed in connection with C−H activation. Detailed ab initio calculations for cyclopropane and cyclohexane on a Cu surface suggest that this anomaly is caused by an unexpected chemical interaction.</abstract><cop>Weinheim</cop><pub>WILEY-VCH Verlag GmbH</pub><pmid>19750699</pmid><doi>10.1002/1521-3773(20020517)41:10<1735::AID-ANIE1735>3.0.CO;2-G</doi><tpages>3</tpages></addata></record>
fulltext	fulltext
identifier	ISSN: 1433-7851
ispartof	Angewandte Chemie International Edition, 2002-05, Vol.41 (10), p.1735-1737
issn	1433-7851 1521-3773
language	eng
recordid	cdi_proquest_miscellaneous_72932991
source	Wiley Online Library Journals Frontfile Complete
subjects	ab initio calculations adsorption alkanes IR spectroscopy surface chemistry
title	The Adsorption of Cyclopropane and Cyclohexane on Cu(111): An Experimental and Theoretical Investigation on the Nature of the CH−Metal Interaction
url	https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-18T11%3A52%3A32IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=The%20Adsorption%20of%20Cyclopropane%20and%20Cyclohexane%20on%20Cu(111):%20An%20Experimental%20and%20Theoretical%20Investigation%20on%20the%20Nature%20of%20the%20CH%E2%88%92Metal%20Interaction&rft.jtitle=Angewandte%20Chemie%20International%20Edition&rft.au=Fosser,%20Kari%20A.&rft.date=2002-05-17&rft.volume=41&rft.issue=10&rft.spage=1735&rft.epage=1737&rft.pages=1735-1737&rft.issn=1433-7851&rft.eissn=1521-3773&rft_id=info:doi/10.1002/1521-3773(20020517)41:10%3C1735::AID-ANIE1735%3E3.0.CO;2-G&rft_dat=%3Cproquest_cross%3E72932991%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=72932991&rft_id=info:pmid/19750699&rfr_iscdi=true