Copolymeric (1 R- trans)- N, N′-1,2-cyclohexylene-bisbenzamide oligodimethylsiloxane chiral stationary phase for gas chromatography
A copolymeric stationary phase, consisting of a chiral selective part, i.e. (1 R- trans)- N, N′-1,2-cyclohexylenebisbenzamide, and an efficient siloxane oligomeric part, was successfully applied to open tubular column GC analysis. The efficiency and the chiral selectivity of this stationary phase we...
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| Veröffentlicht in: | Journal of Chromatography A 2002-12, Vol.982 (1), p.119-126 |
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| container_end_page | 126 |
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| container_issue | 1 |
| container_start_page | 119 |
| container_title | Journal of Chromatography A |
| container_volume | 982 |
| creator | Juvancz, Zoltán Markides, Karin E Petersson, Patrik Johnson, Deborah F Bradshaw, Jerald S Lee, Milton L |
| description | A copolymeric stationary phase, consisting of a chiral selective part, i.e. (1
R-
trans)-
N,
N′-1,2-cyclohexylenebisbenzamide, and an efficient siloxane oligomeric part, was successfully applied to open tubular column GC analysis. The efficiency and the chiral selectivity of this stationary phase were studied in detail, and high capacity and efficiency at elevated GC temperatures were especially noted. Several drugs and other enantiomeric pairs were separated. The shown examples demonstrate a broad application range for this type of chiral stationary phase in GC analysis. |
| doi_str_mv | 10.1016/S0021-9673(02)01428-0 |
| format | Article |
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R-
trans)-
N,
N′-1,2-cyclohexylenebisbenzamide, and an efficient siloxane oligomeric part, was successfully applied to open tubular column GC analysis. The efficiency and the chiral selectivity of this stationary phase were studied in detail, and high capacity and efficiency at elevated GC temperatures were especially noted. Several drugs and other enantiomeric pairs were separated. The shown examples demonstrate a broad application range for this type of chiral stationary phase in GC analysis.</description><identifier>ISSN: 0021-9673</identifier><identifier>DOI: 10.1016/S0021-9673(02)01428-0</identifier><identifier>PMID: 12489861</identifier><identifier>CODEN: JOCRAM</identifier><language>eng</language><publisher>Amsterdam: Elsevier B.V</publisher><subject>Analysis ; Analytical chemistry ; Applied sciences ; Benzamides - chemistry ; Biological and medical sciences ; Chemistry ; Chromatographic methods and physical methods associated with chromatography ; Chromatography, Gas - instrumentation ; Exact sciences and technology ; Gas chromatographic methods ; General pharmacology ; Inorganic and organomineral polymers ; Medical sciences ; Pharmacology. Drug treatments ; Physicochemistry of polymers ; Polymers - chemistry ; Properties and characterization ; Stereoisomerism ; trans-Cyclohexylenebisbenzamide</subject><ispartof>Journal of Chromatography A, 2002-12, Vol.982 (1), p.119-126</ispartof><rights>2002 Elsevier Science B.V.</rights><rights>2003 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c391t-2d8379c5ebe2f66bdcc99c17ef33208e71110975fa2b4723b31730cf15e1a1663</citedby><cites>FETCH-LOGICAL-c391t-2d8379c5ebe2f66bdcc99c17ef33208e71110975fa2b4723b31730cf15e1a1663</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/S0021-9673(02)01428-0$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,780,784,3550,27924,27925,45995</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=14012451$$DView record in Pascal Francis$$Hfree_for_read</backlink><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/12489861$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Juvancz, Zoltán</creatorcontrib><creatorcontrib>Markides, Karin E</creatorcontrib><creatorcontrib>Petersson, Patrik</creatorcontrib><creatorcontrib>Johnson, Deborah F</creatorcontrib><creatorcontrib>Bradshaw, Jerald S</creatorcontrib><creatorcontrib>Lee, Milton L</creatorcontrib><title>Copolymeric (1 R- trans)- N, N′-1,2-cyclohexylene-bisbenzamide oligodimethylsiloxane chiral stationary phase for gas chromatography</title><title>Journal of Chromatography A</title><addtitle>J Chromatogr A</addtitle><description>A copolymeric stationary phase, consisting of a chiral selective part, i.e. (1
R-
trans)-
N,
N′-1,2-cyclohexylenebisbenzamide, and an efficient siloxane oligomeric part, was successfully applied to open tubular column GC analysis. The efficiency and the chiral selectivity of this stationary phase were studied in detail, and high capacity and efficiency at elevated GC temperatures were especially noted. Several drugs and other enantiomeric pairs were separated. The shown examples demonstrate a broad application range for this type of chiral stationary phase in GC analysis.</description><subject>Analysis</subject><subject>Analytical chemistry</subject><subject>Applied sciences</subject><subject>Benzamides - chemistry</subject><subject>Biological and medical sciences</subject><subject>Chemistry</subject><subject>Chromatographic methods and physical methods associated with chromatography</subject><subject>Chromatography, Gas - instrumentation</subject><subject>Exact sciences and technology</subject><subject>Gas chromatographic methods</subject><subject>General pharmacology</subject><subject>Inorganic and organomineral polymers</subject><subject>Medical sciences</subject><subject>Pharmacology. Drug treatments</subject><subject>Physicochemistry of polymers</subject><subject>Polymers - chemistry</subject><subject>Properties and characterization</subject><subject>Stereoisomerism</subject><subject>trans-Cyclohexylenebisbenzamide</subject><issn>0021-9673</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2002</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNqFkM1O3DAQgH1oVSjtI7TyhQok3HrsTZycULUCWgmB1J-z5TiTjSsnDna2Ipy49IX6SDwJWXZVjj2NNPPN30fIO-AfgUP-6TvnAliZK3nExTGHhSgYf0H2_6X3yOuUfnEOiivxiuyBWBRlkcM--bMMQ_BTh9FZegT0G6NjNH06ZvTqhF493P9lcCKYnawPLd5OHntklUsV9nemczXS4N0q1K7DsZ18cj7cmh6pbV00nqbRjC70Jk50aE1C2oRIVybN9Rg6M4ZVNEM7vSEvG-MTvt3FA_Lz_OzH8gu7vL74uvx8yawsYWSiLqQqbYYViibPq9rasrSgsJFS8AIVAPBSZY0R1UIJWUlQktsGMgQDeS4PyIft3CGGmzWmUXcuWfR-Pjmsk1ZCqbIoNmC2BW0MKUVs9BBdN7-hgeuNc_3kXG_kai70k3PN5773uwXrqsP6uWsnfAYOd4BJ1vhmdm1deuYWfEazDXe65XDW8dth1Mk67C3WLqIddR3cf055BGxZocg</recordid><startdate>20021220</startdate><enddate>20021220</enddate><creator>Juvancz, Zoltán</creator><creator>Markides, Karin E</creator><creator>Petersson, Patrik</creator><creator>Johnson, Deborah F</creator><creator>Bradshaw, Jerald S</creator><creator>Lee, Milton L</creator><general>Elsevier B.V</general><general>Elsevier</general><scope>IQODW</scope><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope></search><sort><creationdate>20021220</creationdate><title>Copolymeric (1 R- trans)- N, N′-1,2-cyclohexylene-bisbenzamide oligodimethylsiloxane chiral stationary phase for gas chromatography</title><author>Juvancz, Zoltán ; Markides, Karin E ; Petersson, Patrik ; Johnson, Deborah F ; Bradshaw, Jerald S ; Lee, Milton L</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c391t-2d8379c5ebe2f66bdcc99c17ef33208e71110975fa2b4723b31730cf15e1a1663</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2002</creationdate><topic>Analysis</topic><topic>Analytical chemistry</topic><topic>Applied sciences</topic><topic>Benzamides - chemistry</topic><topic>Biological and medical sciences</topic><topic>Chemistry</topic><topic>Chromatographic methods and physical methods associated with chromatography</topic><topic>Chromatography, Gas - instrumentation</topic><topic>Exact sciences and technology</topic><topic>Gas chromatographic methods</topic><topic>General pharmacology</topic><topic>Inorganic and organomineral polymers</topic><topic>Medical sciences</topic><topic>Pharmacology. Drug treatments</topic><topic>Physicochemistry of polymers</topic><topic>Polymers - chemistry</topic><topic>Properties and characterization</topic><topic>Stereoisomerism</topic><topic>trans-Cyclohexylenebisbenzamide</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Juvancz, Zoltán</creatorcontrib><creatorcontrib>Markides, Karin E</creatorcontrib><creatorcontrib>Petersson, Patrik</creatorcontrib><creatorcontrib>Johnson, Deborah F</creatorcontrib><creatorcontrib>Bradshaw, Jerald S</creatorcontrib><creatorcontrib>Lee, Milton L</creatorcontrib><collection>Pascal-Francis</collection><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><jtitle>Journal of Chromatography A</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Juvancz, Zoltán</au><au>Markides, Karin E</au><au>Petersson, Patrik</au><au>Johnson, Deborah F</au><au>Bradshaw, Jerald S</au><au>Lee, Milton L</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Copolymeric (1 R- trans)- N, N′-1,2-cyclohexylene-bisbenzamide oligodimethylsiloxane chiral stationary phase for gas chromatography</atitle><jtitle>Journal of Chromatography A</jtitle><addtitle>J Chromatogr A</addtitle><date>2002-12-20</date><risdate>2002</risdate><volume>982</volume><issue>1</issue><spage>119</spage><epage>126</epage><pages>119-126</pages><issn>0021-9673</issn><coden>JOCRAM</coden><abstract>A copolymeric stationary phase, consisting of a chiral selective part, i.e. (1
R-
trans)-
N,
N′-1,2-cyclohexylenebisbenzamide, and an efficient siloxane oligomeric part, was successfully applied to open tubular column GC analysis. The efficiency and the chiral selectivity of this stationary phase were studied in detail, and high capacity and efficiency at elevated GC temperatures were especially noted. Several drugs and other enantiomeric pairs were separated. The shown examples demonstrate a broad application range for this type of chiral stationary phase in GC analysis.</abstract><cop>Amsterdam</cop><pub>Elsevier B.V</pub><pmid>12489861</pmid><doi>10.1016/S0021-9673(02)01428-0</doi><tpages>8</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0021-9673 |
| ispartof | Journal of Chromatography A, 2002-12, Vol.982 (1), p.119-126 |
| issn | 0021-9673 |
| language | eng |
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| source | MEDLINE; ScienceDirect Journals (5 years ago - present) |
| subjects | Analysis Analytical chemistry Applied sciences Benzamides - chemistry Biological and medical sciences Chemistry Chromatographic methods and physical methods associated with chromatography Chromatography, Gas - instrumentation Exact sciences and technology Gas chromatographic methods General pharmacology Inorganic and organomineral polymers Medical sciences Pharmacology. Drug treatments Physicochemistry of polymers Polymers - chemistry Properties and characterization Stereoisomerism trans-Cyclohexylenebisbenzamide |
| title | Copolymeric (1 R- trans)- N, N′-1,2-cyclohexylene-bisbenzamide oligodimethylsiloxane chiral stationary phase for gas chromatography |
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