Relative Rates and Approximate Rate Constants for Inter- and Intramolecular Hydrogen Transfer Reactions of Polymer-Bound Radicals

Measurements of relative rates and rate constants for inter- and intramolecular hydrogen transfer reactions of polymer-bound radicals are reported. The relative rate of reaction of resin-bound primary alkyl radical with tributyltin hydride is about 2 times slower than that of the benchmark reaction...

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Veröffentlicht in:	Journal of the American Chemical Society 2002-12, Vol.124 (50), p.14993-15000
Hauptverfasser:	Curran, Dennis P, Yang, Fanglong, Cheong, Jae-ho
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemistry Exact sciences and technology Free radicals chemistry Organic chemistry Reactivity and mechanisms
Online-Zugang:	Volltext
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