Organic Triplet Emissions of Arylacetylide Moieties Harnessed through Coordination to [Au(PCy3)]+. Effect of Molecular Structure upon Photoluminescent Properties

A family of mono- and binuclear Cy3P-supported gold(I) complexes containing various π-conjugated linear arylacetylide ligands, including the two homologous series (Cy3P)Au(C⋮CC6H4) n - 1(C⋮CPh) and (Cy3P)Au(C⋮CC6H4) n C⋮CAu(PCy3) (n = 1−4), have been prepared. X-ray crystal analyses revealed no inte...

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Veröffentlicht in:	Journal of the American Chemical Society 2002-12, Vol.124 (49), p.14696-14706
Hauptverfasser:	Chao, Hsiu-Yi, Lu, Wei, Li, Yanqin, Chan, Michael C. W, Che, Chi-Ming, Cheung, Kung-Kai, Zhu, Nianyong
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemistry Condensed matter: structure, mechanical and thermal properties Coordination compounds Exact sciences and technology Inorganic chemistry and origins of life Inorganic compounds Metal complexes Physics Preparations and properties Structure of solids and liquids crystallography Structure of specific crystalline solids
Online-Zugang:	Volltext
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