N,N,N ‘,N ‘-Tetrakis(2-pyridylmethyl)ethylenediamine and Its Analogues as Hypodentate Ligands. Synthesis and Characterization of the Rhodium(III), Ruthenium(II), and Palladium(II) Complexes
New complexes of Rh(III), Ru(II), and Pd(II) with N,N,N ‘,N ‘-tetrakis(2-pyridylmethyl)ethylenediamine (tpen) and its analogues have been prepared. The reaction of RhCl3·nH2O with tpen is slow and allows one to isolate the products of three consecutive substitution steps: Rh2Cl6(tpen) (1), cis-[RhC...
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| Veröffentlicht in: | Inorganic chemistry 2002-12, Vol.41 (24), p.6237-6243 |
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| Hauptverfasser: | , , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
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