Synthesis, structure and magnetism of a new dicubane-like ferromagnetic tetranuclear nickel cluster containing versatile azido-only bridges and a bis(bidentate) Schiff base blocker

Synthesis, structure and magnetism of a new dicubane-like ferromagnetic tetranuclear nickel cluster containing versatile azido-only bridges and a bis(bidentate) Schiff base blocker

A new tetranuclear double-open dicubane complex [Ni4(mu 2-N3)4(mu 3-N3)2(N3)2(enbzpy)2].2H2O (enbzpy = [N,N-bis(pyridin-2-yl)benzylidene]ethane-1,2-diamine) has been characterised structurally and magnetostructurally.

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2002-01 (20), p.2364-2365
Hauptverfasser: Karmakar, Tapan K, Chandra, Swapan K, Ribas, Joan, Mostafa, Golam, Lu, Tian H, Ghosh, Barindra K
Format: Artikel
Sprache:eng
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Zusammenfassung:A new tetranuclear double-open dicubane complex [Ni4(mu 2-N3)4(mu 3-N3)2(N3)2(enbzpy)2].2H2O (enbzpy = [N,N-bis(pyridin-2-yl)benzylidene]ethane-1,2-diamine) has been characterised structurally and magnetostructurally.
ISSN:1359-7345
1364-548X
DOI:10.1039/b205375f