Structural and Morphological Control of Cationic Surfactant-Templated Mesoporous Silica

Structural and Morphological Control of Cationic Surfactant-Templated Mesoporous Silica

Micelle-templated mesoporous silica materials are rapidly becoming important in many fields of chemistry for hosting reactants or catalysts in confined space. Fine control of the pore size, wall structure, surface functionalization, defects, and morphology is needed for fine-tuning the pores as nano...

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Veröffentlicht in:Accounts of chemical research 2002-11, Vol.35 (11), p.927-935
Hauptverfasser: Lin, Hong-Ping, Mou, Chung-Yuan
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Mou, Chung-Yuan
description Micelle-templated mesoporous silica materials are rapidly becoming important in many fields of chemistry for hosting reactants or catalysts in confined space. Fine control of the pore size, wall structure, surface functionalization, defects, and morphology is needed for fine-tuning the pores as nanoreactors. We review the physical chemistry of solution silicate species and surfactants in the synthesis of mesoporous silicas. Controls in surfactant packing and liquid crystalline phase transformation can lead to various tailored synthesis strategies. Postsynthesis treatments further make more stable mesoporous materials.
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title Structural and Morphological Control of Cationic Surfactant-Templated Mesoporous Silica
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