Inelastic Neutron Scattering Spectroscopy of Diazenides: Detection of the NN Stretch

Inelastic Neutron Scattering Spectroscopy of Diazenides: Detection of the NN Stretch

Birds in a cage: The highly absorbent nitrogen‐rich compounds SrN and SrN2 hide their secrets from Raman scattering experiments, but when observed using inelastic neutron scattering, the dinitrogen can be shown to lie trapped within a cage of strontium atoms. Such a structure is shown in the graphic...

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Veröffentlicht in:Chemphyschem 2002-09, Vol.3 (9), p.815-817
Hauptverfasser: Auffermann, Gudrun, Prots, Yurii, Kniep, Rüdiger, Parker, Stewart F., Bennington, Stephen M.
Format: Artikel
Sprache:eng
Schlagworte:
Analytical chemistry
Chemistry
diazenides
Exact sciences and technology
inelastic neutron spectroscopy
nitrides
Spectrometric and optical methods
vibrational spectroscopy
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Beschreibung
Zusammenfassung:Birds in a cage: The highly absorbent nitrogen‐rich compounds SrN and SrN2 hide their secrets from Raman scattering experiments, but when observed using inelastic neutron scattering, the dinitrogen can be shown to lie trapped within a cage of strontium atoms. Such a structure is shown in the graphic for SrN2, in which the dumbbell‐shaped dinitrogen can be clearly identified.
ISSN:1439-4235
1439-7641
DOI:10.1002/1439-7641(20020916)3:9<815::AID-CPHC815>3.0.CO;2-1