Pair-wise interactions by gas chromatography: VII. Interaction free enthalpies of solutes with secondary alcohol groups
A polar type liquid having a secondary alcohol substituent on a branched alkane skeleton, SOH, was used as stationary phase. The molecules of this stationary phase are nearly isomorphous and isochor with those of the branched alkane, C 78, elected as standard, i.e., the molecules of both solvents ha...
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| Veröffentlicht in: | Journal of Chromatography A 2000-12, Vol.904 (2), p.211-242 |
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| container_title | Journal of Chromatography A |
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| creator | Dallos, András Sisak, Attila Kulcsár, Zita Kováts, Ervin sz |
| description | A polar type liquid having a secondary alcohol substituent on a branched alkane skeleton, SOH, was used as stationary phase. The molecules of this stationary phase are nearly isomorphous and isochor with those of the branched alkane, C
78, elected as standard, i.e., the molecules of both solvents have nearly the same form and the same size. Partition properties of 158 chosen molecular probes were measured by gas chromatography on SOH and on an SOH–C
78 mixture having a volume fraction of
ϕ
SOH=0.5. Based on the resulting data an interaction free enthalpy could be calculated, i.e., the additional effect of the secondary alcohol to partition. Comparison with data determined earlier on another member of this solvent family, POH, having a primary alcohol as interacting group gives information about the effect of steric hindrance on polar type solute–solvent interaction free energies. |
| doi_str_mv | 10.1016/S0021-9673(00)00908-0 |
| format | Article |
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78, elected as standard, i.e., the molecules of both solvents have nearly the same form and the same size. Partition properties of 158 chosen molecular probes were measured by gas chromatography on SOH and on an SOH–C
78 mixture having a volume fraction of
ϕ
SOH=0.5. Based on the resulting data an interaction free enthalpy could be calculated, i.e., the additional effect of the secondary alcohol to partition. Comparison with data determined earlier on another member of this solvent family, POH, having a primary alcohol as interacting group gives information about the effect of steric hindrance on polar type solute–solvent interaction free energies.</description><identifier>ISSN: 0021-9673</identifier><identifier>DOI: 10.1016/S0021-9673(00)00908-0</identifier><identifier>PMID: 11204236</identifier><identifier>CODEN: JOCRAM</identifier><language>eng</language><publisher>Amsterdam: Elsevier B.V</publisher><subject>Alcohols ; Alcohols - chemistry ; Aldehydes ; Alkanes ; Alkanones ; Alkenes ; Alkynes ; Amines ; Analytical chemistry ; Benzenes ; Chemistry ; Chromatographic methods and physical methods associated with chromatography ; Chromatography, Gas - methods ; Ethers ; Exact sciences and technology ; Gas chromatographic methods ; Pyridines ; Thermodynamics ; Thiols</subject><ispartof>Journal of Chromatography A, 2000-12, Vol.904 (2), p.211-242</ispartof><rights>2000 Elsevier Science B.V.</rights><rights>2001 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/S0021-9673(00)00908-0$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,780,784,3548,27922,27923,45993</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=861480$$DView record in Pascal Francis$$Hfree_for_read</backlink><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/11204236$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Dallos, András</creatorcontrib><creatorcontrib>Sisak, Attila</creatorcontrib><creatorcontrib>Kulcsár, Zita</creatorcontrib><creatorcontrib>Kováts, Ervin sz</creatorcontrib><title>Pair-wise interactions by gas chromatography: VII. Interaction free enthalpies of solutes with secondary alcohol groups</title><title>Journal of Chromatography A</title><addtitle>J Chromatogr A</addtitle><description>A polar type liquid having a secondary alcohol substituent on a branched alkane skeleton, SOH, was used as stationary phase. The molecules of this stationary phase are nearly isomorphous and isochor with those of the branched alkane, C
78, elected as standard, i.e., the molecules of both solvents have nearly the same form and the same size. Partition properties of 158 chosen molecular probes were measured by gas chromatography on SOH and on an SOH–C
78 mixture having a volume fraction of
ϕ
SOH=0.5. Based on the resulting data an interaction free enthalpy could be calculated, i.e., the additional effect of the secondary alcohol to partition. Comparison with data determined earlier on another member of this solvent family, POH, having a primary alcohol as interacting group gives information about the effect of steric hindrance on polar type solute–solvent interaction free energies.</description><subject>Alcohols</subject><subject>Alcohols - chemistry</subject><subject>Aldehydes</subject><subject>Alkanes</subject><subject>Alkanones</subject><subject>Alkenes</subject><subject>Alkynes</subject><subject>Amines</subject><subject>Analytical chemistry</subject><subject>Benzenes</subject><subject>Chemistry</subject><subject>Chromatographic methods and physical methods associated with chromatography</subject><subject>Chromatography, Gas - methods</subject><subject>Ethers</subject><subject>Exact sciences and technology</subject><subject>Gas chromatographic methods</subject><subject>Pyridines</subject><subject>Thermodynamics</subject><subject>Thiols</subject><issn>0021-9673</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2000</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNpF0VFrFDEQB_A8KG1t_QhKQBB92DrJ7iZZX0SKtgeFCra-hrns7G1kb7MmWY_79m7bs33KEH4MM_Nn7I2AcwFCffoJIEXRKF1-APgI0IAp4AU7efo-Zq9S-g0gNGh5xI6FkFDJUp2w3Q_0sdj5RNyPmSK67MOY-HrPN5i462PYYg6biFO__8x_rVbnfPUMeReJOI25x2HylHjoeArDnJdy53PPE7kwthj3HAcX-jDwTQzzlM7Yyw6HRK8P7ym7-_7t9uKquL65XF18vS5I1jIXUrbCVMpoQ11dq1LoTpSkCZ0SStbYNA2uyZgKwZS4GG00AJraiZrc2pWn7P1j3ymGPzOlbLc-ORoGHCnMyWpZV1JKtcC3Bzivt9TaKfrtMrb9f6oFvDsATA6HLuLofHpyRonKwKK-PCpalvrrKdrkPI2OWh_JZdsGbwXY-9jsQ2z2Ph8LYB9is1D-A1XujB8</recordid><startdate>20001229</startdate><enddate>20001229</enddate><creator>Dallos, András</creator><creator>Sisak, Attila</creator><creator>Kulcsár, Zita</creator><creator>Kováts, Ervin sz</creator><general>Elsevier B.V</general><general>Elsevier</general><scope>IQODW</scope><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>7X8</scope></search><sort><creationdate>20001229</creationdate><title>Pair-wise interactions by gas chromatography: VII. Interaction free enthalpies of solutes with secondary alcohol groups</title><author>Dallos, András ; Sisak, Attila ; Kulcsár, Zita ; Kováts, Ervin sz</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-e252t-22d1846878ef556317f13e7eac61625a999abe884a083aef578700a85c15ecbc3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2000</creationdate><topic>Alcohols</topic><topic>Alcohols - chemistry</topic><topic>Aldehydes</topic><topic>Alkanes</topic><topic>Alkanones</topic><topic>Alkenes</topic><topic>Alkynes</topic><topic>Amines</topic><topic>Analytical chemistry</topic><topic>Benzenes</topic><topic>Chemistry</topic><topic>Chromatographic methods and physical methods associated with chromatography</topic><topic>Chromatography, Gas - methods</topic><topic>Ethers</topic><topic>Exact sciences and technology</topic><topic>Gas chromatographic methods</topic><topic>Pyridines</topic><topic>Thermodynamics</topic><topic>Thiols</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Dallos, András</creatorcontrib><creatorcontrib>Sisak, Attila</creatorcontrib><creatorcontrib>Kulcsár, Zita</creatorcontrib><creatorcontrib>Kováts, Ervin sz</creatorcontrib><collection>Pascal-Francis</collection><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>MEDLINE - Academic</collection><jtitle>Journal of Chromatography A</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Dallos, András</au><au>Sisak, Attila</au><au>Kulcsár, Zita</au><au>Kováts, Ervin sz</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Pair-wise interactions by gas chromatography: VII. Interaction free enthalpies of solutes with secondary alcohol groups</atitle><jtitle>Journal of Chromatography A</jtitle><addtitle>J Chromatogr A</addtitle><date>2000-12-29</date><risdate>2000</risdate><volume>904</volume><issue>2</issue><spage>211</spage><epage>242</epage><pages>211-242</pages><issn>0021-9673</issn><coden>JOCRAM</coden><abstract>A polar type liquid having a secondary alcohol substituent on a branched alkane skeleton, SOH, was used as stationary phase. The molecules of this stationary phase are nearly isomorphous and isochor with those of the branched alkane, C
78, elected as standard, i.e., the molecules of both solvents have nearly the same form and the same size. Partition properties of 158 chosen molecular probes were measured by gas chromatography on SOH and on an SOH–C
78 mixture having a volume fraction of
ϕ
SOH=0.5. Based on the resulting data an interaction free enthalpy could be calculated, i.e., the additional effect of the secondary alcohol to partition. Comparison with data determined earlier on another member of this solvent family, POH, having a primary alcohol as interacting group gives information about the effect of steric hindrance on polar type solute–solvent interaction free energies.</abstract><cop>Amsterdam</cop><pub>Elsevier B.V</pub><pmid>11204236</pmid><doi>10.1016/S0021-9673(00)00908-0</doi><tpages>32</tpages></addata></record> |
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| source | MEDLINE; Elsevier ScienceDirect Journals Complete |
| subjects | Alcohols Alcohols - chemistry Aldehydes Alkanes Alkanones Alkenes Alkynes Amines Analytical chemistry Benzenes Chemistry Chromatographic methods and physical methods associated with chromatography Chromatography, Gas - methods Ethers Exact sciences and technology Gas chromatographic methods Pyridines Thermodynamics Thiols |
| title | Pair-wise interactions by gas chromatography: VII. Interaction free enthalpies of solutes with secondary alcohol groups |
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