Evaluation of carrier gases for use in high-field asymmetric waveform ion mobility spectrometry
Effects of carrier gas type (N 2, O 2, CO 2, N 2O, and SF 6) on changes in the ratio of high- to low-field ion mobility, K h / K, of cesium, gramicidin S, tetrahexylammonium, heptadecanoic acid, and aspartic acid in fields of up to 67 Td are presented. The theory of the mobility of ions at high E/ N...
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| Veröffentlicht in: | Journal of the American Society for Mass Spectrometry 2000-12, Vol.11 (12), p.1125-1133 |
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| creator | Barnett, David A Ells, Barbara Guevremont, Roger Purves, Randy W Viehland, Larry A |
| description | Effects of carrier gas type (N
2, O
2, CO
2, N
2O, and SF
6) on changes in the ratio of high- to low-field ion mobility,
K
h
/
K, of cesium, gramicidin S, tetrahexylammonium, heptadecanoic acid, and aspartic acid in fields of up to 67 Td are presented. The theory of the mobility of ions at high
E/
N in different gases is discussed. Plots of
K
h
/
K as a function of the ionic energy parameter,
E/
N, for the five ions in each of the gases were derived from experimental data collected using a high-field asymmetric waveform ion mobility spectrometer. The change in the ratio of high- to low-field ion mobility of cesium in carrier gases of O
2 and N
2 showed excellent agreement with literature values. The behavior of cesium in O
2 and N
2 is used to illustrate that the ratio
K
h
/
K as a function of effective temperature is invariant with gas type as long as the well depth of the interaction potential significantly exceeds thermal energy. From these results, it appears that the well depth of the interaction potential of the heavier ions studied here, including gramicidin S, tetrahexylammonium, and heptadecanoic acid, with bath gases such as N
2 and O
2, is shallow relative to thermal energy. |
| doi_str_mv | 10.1016/S1044-0305(00)00187-2 |
| format | Article |
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2, O
2, CO
2, N
2O, and SF
6) on changes in the ratio of high- to low-field ion mobility,
K
h
/
K, of cesium, gramicidin S, tetrahexylammonium, heptadecanoic acid, and aspartic acid in fields of up to 67 Td are presented. The theory of the mobility of ions at high
E/
N in different gases is discussed. Plots of
K
h
/
K as a function of the ionic energy parameter,
E/
N, for the five ions in each of the gases were derived from experimental data collected using a high-field asymmetric waveform ion mobility spectrometer. The change in the ratio of high- to low-field ion mobility of cesium in carrier gases of O
2 and N
2 showed excellent agreement with literature values. The behavior of cesium in O
2 and N
2 is used to illustrate that the ratio
K
h
/
K as a function of effective temperature is invariant with gas type as long as the well depth of the interaction potential significantly exceeds thermal energy. From these results, it appears that the well depth of the interaction potential of the heavier ions studied here, including gramicidin S, tetrahexylammonium, and heptadecanoic acid, with bath gases such as N
2 and O
2, is shallow relative to thermal energy.</description><identifier>ISSN: 1044-0305</identifier><identifier>EISSN: 1879-1123</identifier><identifier>DOI: 10.1016/S1044-0305(00)00187-2</identifier><identifier>PMID: 11118120</identifier><language>eng</language><publisher>New York, NY: Elsevier Inc</publisher><subject>Aminoacids, peptides. Hormones. Neuropeptides ; Analytical chemistry ; Analytical, structural and metabolic biochemistry ; Aspartic acid ; Biological and medical sciences ; Carrier gases ; Cesium ; Chemistry ; Exact sciences and technology ; Fundamental and applied biological sciences. Psychology ; Ionic mobility ; Ions ; Mass spectrometry ; Proteins ; Spectrometric and optical methods ; Thermal energy</subject><ispartof>Journal of the American Society for Mass Spectrometry, 2000-12, Vol.11 (12), p.1125-1133</ispartof><rights>2000 American Society for Mass Spectrometry</rights><rights>2001 INIST-CNRS</rights><rights>American Society for Mass Spectrometry 2000</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c481t-9a6e463ad9e7790b8e9c61a2ce908d9a3ba3f2d080247ac1429719a4013657a83</citedby><cites>FETCH-LOGICAL-c481t-9a6e463ad9e7790b8e9c61a2ce908d9a3ba3f2d080247ac1429719a4013657a83</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=844289$$DView record in Pascal Francis$$Hfree_for_read</backlink><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/11118120$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Barnett, David A</creatorcontrib><creatorcontrib>Ells, Barbara</creatorcontrib><creatorcontrib>Guevremont, Roger</creatorcontrib><creatorcontrib>Purves, Randy W</creatorcontrib><creatorcontrib>Viehland, Larry A</creatorcontrib><title>Evaluation of carrier gases for use in high-field asymmetric waveform ion mobility spectrometry</title><title>Journal of the American Society for Mass Spectrometry</title><addtitle>J Am Soc Mass Spectrom</addtitle><description>Effects of carrier gas type (N
2, O
2, CO
2, N
2O, and SF
6) on changes in the ratio of high- to low-field ion mobility,
K
h
/
K, of cesium, gramicidin S, tetrahexylammonium, heptadecanoic acid, and aspartic acid in fields of up to 67 Td are presented. The theory of the mobility of ions at high
E/
N in different gases is discussed. Plots of
K
h
/
K as a function of the ionic energy parameter,
E/
N, for the five ions in each of the gases were derived from experimental data collected using a high-field asymmetric waveform ion mobility spectrometer. The change in the ratio of high- to low-field ion mobility of cesium in carrier gases of O
2 and N
2 showed excellent agreement with literature values. The behavior of cesium in O
2 and N
2 is used to illustrate that the ratio
K
h
/
K as a function of effective temperature is invariant with gas type as long as the well depth of the interaction potential significantly exceeds thermal energy. From these results, it appears that the well depth of the interaction potential of the heavier ions studied here, including gramicidin S, tetrahexylammonium, and heptadecanoic acid, with bath gases such as N
2 and O
2, is shallow relative to thermal energy.</description><subject>Aminoacids, peptides. Hormones. Neuropeptides</subject><subject>Analytical chemistry</subject><subject>Analytical, structural and metabolic biochemistry</subject><subject>Aspartic acid</subject><subject>Biological and medical sciences</subject><subject>Carrier gases</subject><subject>Cesium</subject><subject>Chemistry</subject><subject>Exact sciences and technology</subject><subject>Fundamental and applied biological sciences. Psychology</subject><subject>Ionic mobility</subject><subject>Ions</subject><subject>Mass spectrometry</subject><subject>Proteins</subject><subject>Spectrometric and optical methods</subject><subject>Thermal energy</subject><issn>1044-0305</issn><issn>1879-1123</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2000</creationdate><recordtype>article</recordtype><sourceid>8G5</sourceid><sourceid>ABUWG</sourceid><sourceid>AFKRA</sourceid><sourceid>AZQEC</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><sourceid>GNUQQ</sourceid><sourceid>GUQSH</sourceid><sourceid>M2O</sourceid><recordid>eNqFkcFu1DAQhq2qiJbCIxRZqoTgEBg73tg-IVS1gFSJQ9uzNetMWldJvNjJVvv2eLtbQFyYy8zh-8ejz4ydCvgoQDSfrgUoVUENi_cAHwCE0ZU8YMel20oIWR-W-Rk5Yq9yfiiQBqtfsiNRyggJx8xdrLGfcQpx5LHjHlMKlPgdZsq8i4nPmXgY-X24u6-6QH3LMW-GgaYUPH_ENRVo4Nv4EJehD9OG5xX5KcUts3nNXnTYZ3qz7yfs9vLi5vxbdfXj6_fzL1eVV0ZMlcWGVFNja0lrC0tD1jcCpScLprVYL7HuZAsGpNLohZJWC4sKRN0sNJr6hL3b7V2l-HOmPLkhZE99jyPFOTstlS0iRAHP_gEf4pzGcpsTdiFVbZRVhVrsKJ9izok6t0phwLRxAtzWv3vy77ZyHYB78u9kyb3db5-XA7V_Unvhfz2P2WPfJRx9yL85o5Q0tlCfdxQVZevyIS77QKOnNqTi1rUx_OeQX3yboK0</recordid><startdate>20001201</startdate><enddate>20001201</enddate><creator>Barnett, David A</creator><creator>Ells, Barbara</creator><creator>Guevremont, Roger</creator><creator>Purves, Randy W</creator><creator>Viehland, Larry A</creator><general>Elsevier Inc</general><general>Elsevier Science</general><general>Springer Nature B.V</general><scope>6I.</scope><scope>AAFTH</scope><scope>IQODW</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>3V.</scope><scope>7X7</scope><scope>7XB</scope><scope>88E</scope><scope>8FE</scope><scope>8FG</scope><scope>8FI</scope><scope>8FJ</scope><scope>8FK</scope><scope>8G5</scope><scope>ABUWG</scope><scope>AFKRA</scope><scope>ARAPS</scope><scope>AZQEC</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>DWQXO</scope><scope>FYUFA</scope><scope>GHDGH</scope><scope>GNUQQ</scope><scope>GUQSH</scope><scope>HCIFZ</scope><scope>K9.</scope><scope>M0S</scope><scope>M1P</scope><scope>M2O</scope><scope>MBDVC</scope><scope>P5Z</scope><scope>P62</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope><scope>Q9U</scope><scope>7X8</scope></search><sort><creationdate>20001201</creationdate><title>Evaluation of carrier gases for use in high-field asymmetric waveform ion mobility spectrometry</title><author>Barnett, David A ; Ells, Barbara ; Guevremont, Roger ; Purves, Randy W ; Viehland, Larry A</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c481t-9a6e463ad9e7790b8e9c61a2ce908d9a3ba3f2d080247ac1429719a4013657a83</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2000</creationdate><topic>Aminoacids, peptides. Hormones. Neuropeptides</topic><topic>Analytical chemistry</topic><topic>Analytical, structural and metabolic biochemistry</topic><topic>Aspartic acid</topic><topic>Biological and medical sciences</topic><topic>Carrier gases</topic><topic>Cesium</topic><topic>Chemistry</topic><topic>Exact sciences and technology</topic><topic>Fundamental and applied biological sciences. Psychology</topic><topic>Ionic mobility</topic><topic>Ions</topic><topic>Mass spectrometry</topic><topic>Proteins</topic><topic>Spectrometric and optical methods</topic><topic>Thermal energy</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Barnett, David A</creatorcontrib><creatorcontrib>Ells, Barbara</creatorcontrib><creatorcontrib>Guevremont, Roger</creatorcontrib><creatorcontrib>Purves, Randy W</creatorcontrib><creatorcontrib>Viehland, Larry A</creatorcontrib><collection>ScienceDirect Open Access Titles</collection><collection>Elsevier:ScienceDirect:Open Access</collection><collection>Pascal-Francis</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>ProQuest Central (Corporate)</collection><collection>Health & Medical Collection</collection><collection>ProQuest Central (purchase pre-March 2016)</collection><collection>Medical Database (Alumni Edition)</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Hospital Premium Collection</collection><collection>Hospital Premium Collection (Alumni Edition)</collection><collection>ProQuest Central (Alumni) (purchase pre-March 2016)</collection><collection>Research Library (Alumni Edition)</collection><collection>ProQuest Central (Alumni Edition)</collection><collection>ProQuest Central UK/Ireland</collection><collection>Advanced Technologies & Aerospace Collection</collection><collection>ProQuest Central Essentials</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Central Korea</collection><collection>Health Research Premium Collection</collection><collection>Health Research Premium Collection (Alumni)</collection><collection>ProQuest Central Student</collection><collection>Research Library Prep</collection><collection>SciTech Premium Collection</collection><collection>ProQuest Health & Medical Complete (Alumni)</collection><collection>Health & Medical Collection (Alumni Edition)</collection><collection>Medical Database</collection><collection>Research Library</collection><collection>Research Library (Corporate)</collection><collection>Advanced Technologies & Aerospace Database</collection><collection>ProQuest Advanced Technologies & Aerospace Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><collection>ProQuest Central Basic</collection><collection>MEDLINE - Academic</collection><jtitle>Journal of the American Society for Mass Spectrometry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Barnett, David A</au><au>Ells, Barbara</au><au>Guevremont, Roger</au><au>Purves, Randy W</au><au>Viehland, Larry A</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Evaluation of carrier gases for use in high-field asymmetric waveform ion mobility spectrometry</atitle><jtitle>Journal of the American Society for Mass Spectrometry</jtitle><addtitle>J Am Soc Mass Spectrom</addtitle><date>2000-12-01</date><risdate>2000</risdate><volume>11</volume><issue>12</issue><spage>1125</spage><epage>1133</epage><pages>1125-1133</pages><issn>1044-0305</issn><eissn>1879-1123</eissn><abstract>Effects of carrier gas type (N
2, O
2, CO
2, N
2O, and SF
6) on changes in the ratio of high- to low-field ion mobility,
K
h
/
K, of cesium, gramicidin S, tetrahexylammonium, heptadecanoic acid, and aspartic acid in fields of up to 67 Td are presented. The theory of the mobility of ions at high
E/
N in different gases is discussed. Plots of
K
h
/
K as a function of the ionic energy parameter,
E/
N, for the five ions in each of the gases were derived from experimental data collected using a high-field asymmetric waveform ion mobility spectrometer. The change in the ratio of high- to low-field ion mobility of cesium in carrier gases of O
2 and N
2 showed excellent agreement with literature values. The behavior of cesium in O
2 and N
2 is used to illustrate that the ratio
K
h
/
K as a function of effective temperature is invariant with gas type as long as the well depth of the interaction potential significantly exceeds thermal energy. From these results, it appears that the well depth of the interaction potential of the heavier ions studied here, including gramicidin S, tetrahexylammonium, and heptadecanoic acid, with bath gases such as N
2 and O
2, is shallow relative to thermal energy.</abstract><cop>New York, NY</cop><pub>Elsevier Inc</pub><pmid>11118120</pmid><doi>10.1016/S1044-0305(00)00187-2</doi><tpages>9</tpages><oa>free_for_read</oa></addata></record> |
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| source | SpringerNature Journals; EZB-FREE-00999 freely available EZB journals; Alma/SFX Local Collection; Free Full-Text Journals in Chemistry |
| subjects | Aminoacids, peptides. Hormones. Neuropeptides Analytical chemistry Analytical, structural and metabolic biochemistry Aspartic acid Biological and medical sciences Carrier gases Cesium Chemistry Exact sciences and technology Fundamental and applied biological sciences. Psychology Ionic mobility Ions Mass spectrometry Proteins Spectrometric and optical methods Thermal energy |
| title | Evaluation of carrier gases for use in high-field asymmetric waveform ion mobility spectrometry |
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