Application of Rh-Catalyzed Cyclization to the Formation of a Chiral Quaternary Carbon

Rh-Catalyzed cyclization was applied to the formation of a chiral quaternary carbon. It has become clear that the Rh-complex can discriminate between isopropenyl and 2-isopentenyl (or isopentyl) substituents, and the cyclization afforded 3, 3, 4-trisubstituted cyclopentanones with a chiral quaternar...

Ausführliche Beschreibung