The role of germacrene D as a precursor in sesquiterpene biosynthesis: investigations of acid catalyzed, photochemically and thermally induced rearrangements

Germacrene D is considered as a precursor of many sesquiterpene hydrocarbons. We have investigated the acid catalyzed as well as the photochemically and thermally induced rearrangement processes of germacrene D isolated from several Solidago species, which contain both enantiomers of germacrene D. E...

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Veröffentlicht in:	Phytochemistry (Oxford) 2000-09, Vol.55 (2), p.141-168
Hauptverfasser:	Bülow, N, Konig, W A
Format:	Artikel
Sprache:	eng
Schlagworte:	Acids Agronomy. Soil science and plant productions Biological and medical sciences Carbocations Catalysis Chromatography, Gas Economic plant physiology Fundamental and applied biological sciences. Psychology Germacrene D Hot Temperature Isogermacrene D Magnetic Resonance Spectroscopy Mass Spectrometry Metabolism Metabolism. Physicochemical requirements Molecular Structure Nitrogen metabolism and other ones (excepting carbon metabolism) Nutrition. Photosynthesis. Respiration. Metabolism Photochemistry Plant physiology and development Rearrangement Sesquiterpenes Sesquiterpenes - chemistry Sesquiterpenes - metabolism Sesquiterpenes, Germacrane Solidago spec Thermochemistry
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