Quenching effect of triethylamine on peroxyoxalate chemiluminescence in the presence of 7-amino-4-trifluoromethylcumarin
The quenching effect of triethylamine on strong chemiluminescence of bis-(2,4,6-trichlorophenyl)oxalate–hydrogen peroxide system in the presence of 7-amino-4-trifluoromethylcumarin was studied. The system resulted in a nice Stern–Volmer plot with a k Q value of 1.07×10 −3 M −1, in the quencher conce...
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Veröffentlicht in: | Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy Molecular and biomolecular spectroscopy, 2001-10, Vol.57 (12), p.2355-2358 |
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container_title | Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy |
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creator | Shamsipur, Mojtaba Chaichi, Mohammad Javad |
description | The quenching effect of triethylamine on strong chemiluminescence of bis-(2,4,6-trichlorophenyl)oxalate–hydrogen peroxide system in the presence of 7-amino-4-trifluoromethylcumarin was studied. The system resulted in a nice Stern–Volmer plot with a
k
Q value of 1.07×10
−3 M
−1, in the quencher concentration range of 1.52×10
−4–1.36×10
−3 M. The linear correlation between the decay rate constant of the resulting chemiluminescence and the quencher concentration was also investigated. |
doi_str_mv | 10.1016/S1386-1425(01)00396-1 |
format | Article |
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k
Q value of 1.07×10
−3 M
−1, in the quencher concentration range of 1.52×10
−4–1.36×10
−3 M. The linear correlation between the decay rate constant of the resulting chemiluminescence and the quencher concentration was also investigated.</description><identifier>ISSN: 1386-1425</identifier><identifier>DOI: 10.1016/S1386-1425(01)00396-1</identifier><identifier>PMID: 11767829</identifier><language>eng</language><publisher>England: Elsevier B.V</publisher><subject>Chemiluminescence ; Coumarins - chemistry ; Ethylamines - chemistry ; Fluorescence ; Kinetics ; Luminescent Measurements ; Models, Chemical ; Oxalates - chemistry ; Peroxyoxalate ; Quenching effect ; Spectrometry, Fluorescence ; Triethylamine</subject><ispartof>Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 2001-10, Vol.57 (12), p.2355-2358</ispartof><rights>2001 Elsevier Science B.V.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c361t-60ab3b409ce9528ccfc2e091e9f66375e07e33ba2179c8b6c19d3e5e496f72db3</citedby><cites>FETCH-LOGICAL-c361t-60ab3b409ce9528ccfc2e091e9f66375e07e33ba2179c8b6c19d3e5e496f72db3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/S1386-1425(01)00396-1$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,780,784,3550,27924,27925,45995</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/11767829$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Shamsipur, Mojtaba</creatorcontrib><creatorcontrib>Chaichi, Mohammad Javad</creatorcontrib><title>Quenching effect of triethylamine on peroxyoxalate chemiluminescence in the presence of 7-amino-4-trifluoromethylcumarin</title><title>Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy</title><addtitle>Spectrochim Acta A Mol Biomol Spectrosc</addtitle><description>The quenching effect of triethylamine on strong chemiluminescence of bis-(2,4,6-trichlorophenyl)oxalate–hydrogen peroxide system in the presence of 7-amino-4-trifluoromethylcumarin was studied. The system resulted in a nice Stern–Volmer plot with a
k
Q value of 1.07×10
−3 M
−1, in the quencher concentration range of 1.52×10
−4–1.36×10
−3 M. The linear correlation between the decay rate constant of the resulting chemiluminescence and the quencher concentration was also investigated.</description><subject>Chemiluminescence</subject><subject>Coumarins - chemistry</subject><subject>Ethylamines - chemistry</subject><subject>Fluorescence</subject><subject>Kinetics</subject><subject>Luminescent Measurements</subject><subject>Models, Chemical</subject><subject>Oxalates - chemistry</subject><subject>Peroxyoxalate</subject><subject>Quenching effect</subject><subject>Spectrometry, Fluorescence</subject><subject>Triethylamine</subject><issn>1386-1425</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2001</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNqFkM1OwzAQhH0A0VJ4BJBPCA4BO27s-IRQxZ-EhBBwthJnTY2SuNgJat8eJ63gyMla78zs7ofQCSWXlFB-9UpZzhM6T7NzQi8IYTJWe2j6-z1BhyF8EkJonpIDNKFUcJGncorWLz20emnbDwzGgO6wM7jzFrrlpi4a2wJ2LV6Bd-uNWxd10QHWS2hs3Q_NoKMbsG1xtwS88hDGOmaIZHC7ZJ7ENFP3zrtmDNV9U3jbHqF9U9QBjnfvDL3f3b4tHpKn5_vHxc1TohmnXcJJUbJyTqQGmaW51kanQCQFaThnIgMigLGySKmQOi-5prJikMFcciPSqmQzdLbNXXn31UPoVGPj1nVdtOD6oETKIgqRR2G2FWrvQvBg1MrbuOpGUaIGzGrErAaeilA1YlY0-k53A_qygerPtWMcBddbAcQzvy14FbQdMFXWR-CqcvafET9dLZHV</recordid><startdate>20011001</startdate><enddate>20011001</enddate><creator>Shamsipur, Mojtaba</creator><creator>Chaichi, Mohammad Javad</creator><general>Elsevier B.V</general><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope></search><sort><creationdate>20011001</creationdate><title>Quenching effect of triethylamine on peroxyoxalate chemiluminescence in the presence of 7-amino-4-trifluoromethylcumarin</title><author>Shamsipur, Mojtaba ; Chaichi, Mohammad Javad</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c361t-60ab3b409ce9528ccfc2e091e9f66375e07e33ba2179c8b6c19d3e5e496f72db3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2001</creationdate><topic>Chemiluminescence</topic><topic>Coumarins - chemistry</topic><topic>Ethylamines - chemistry</topic><topic>Fluorescence</topic><topic>Kinetics</topic><topic>Luminescent Measurements</topic><topic>Models, Chemical</topic><topic>Oxalates - chemistry</topic><topic>Peroxyoxalate</topic><topic>Quenching effect</topic><topic>Spectrometry, Fluorescence</topic><topic>Triethylamine</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Shamsipur, Mojtaba</creatorcontrib><creatorcontrib>Chaichi, Mohammad Javad</creatorcontrib><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><jtitle>Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Shamsipur, Mojtaba</au><au>Chaichi, Mohammad Javad</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Quenching effect of triethylamine on peroxyoxalate chemiluminescence in the presence of 7-amino-4-trifluoromethylcumarin</atitle><jtitle>Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy</jtitle><addtitle>Spectrochim Acta A Mol Biomol Spectrosc</addtitle><date>2001-10-01</date><risdate>2001</risdate><volume>57</volume><issue>12</issue><spage>2355</spage><epage>2358</epage><pages>2355-2358</pages><issn>1386-1425</issn><abstract>The quenching effect of triethylamine on strong chemiluminescence of bis-(2,4,6-trichlorophenyl)oxalate–hydrogen peroxide system in the presence of 7-amino-4-trifluoromethylcumarin was studied. The system resulted in a nice Stern–Volmer plot with a
k
Q value of 1.07×10
−3 M
−1, in the quencher concentration range of 1.52×10
−4–1.36×10
−3 M. The linear correlation between the decay rate constant of the resulting chemiluminescence and the quencher concentration was also investigated.</abstract><cop>England</cop><pub>Elsevier B.V</pub><pmid>11767829</pmid><doi>10.1016/S1386-1425(01)00396-1</doi><tpages>4</tpages></addata></record> |
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subjects | Chemiluminescence Coumarins - chemistry Ethylamines - chemistry Fluorescence Kinetics Luminescent Measurements Models, Chemical Oxalates - chemistry Peroxyoxalate Quenching effect Spectrometry, Fluorescence Triethylamine |
title | Quenching effect of triethylamine on peroxyoxalate chemiluminescence in the presence of 7-amino-4-trifluoromethylcumarin |
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