Lipase-catalyzed synthesis of geranyl acetate in n-hexane with membrane-mediated water removal

The esterification of geraniol with acetic acid in n‐hexane was investigated. A commercial lipase preparation from Candida antarctica was used as catalyst. The equilibrium conversion (no water removal) was found to be 94% for the reaction of 0.1 M alcohol and 0.1 M acid in n‐hexane at 30°C. This was...

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Veröffentlicht in:	Biotechnology and bioengineering 2001-12, Vol.75 (6), p.676-681
Hauptverfasser:	Bartling, Karsten, Thompson, Judith U. S., Pfromm, Peter H., Czermak, Peter, Rezac, Mary E.
Format:	Artikel
Sprache:	eng
Schlagworte:	Acetates - chemical synthesis Bioconversions. Hemisynthesis Biological and medical sciences Biotechnology Candida antarctica Catalysis esterification Fundamental and applied biological sciences. Psychology Hexanes - chemistry Lipase - chemistry membrane Membranes, Artificial Methods. Procedures. Technologies pervaporation Terpenes - chemical synthesis Thermodynamics Water
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