Stereocontrol in Cyclophane Synthesis:  A Photochemical Method To Overlap Aromatic Rings

To overlap aromatic rings in cyclophanes, the inter- and intramolecular [2 + 2] photocycloaddition of vinylarenes has been developed. It gives cyclophanes, naphthalenophanes, phenanthrenophanes, thiophenophanes, and carbazolophanes in reasonable to excellent yields. The structures and properties of...

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Veröffentlicht in:	Accounts of chemical research 2000-10, Vol.33 (10), p.679-686
Hauptverfasser:	Nishimura, Jun, Nakamura, Yosuke, Hayashida, Yoshitou, Kudo, Takako
Format:	Artikel
Sprache:	eng
Schlagworte:	Cyclobutanes - chemistry Ethers, Cyclic - chemical synthesis Ethers, Cyclic - chemistry Fluorescence Molecular Structure Photochemistry Stereoisomerism
Online-Zugang:	Volltext
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