Synthesis of Benzo-Fused 1-Azabicyclo[m.n.0]alkanes via the Schmidt Reaction:  A Formal Synthesis of Gephyrotoxin

The intramolecular capture of benzocyclobutyl, benzocyclopentyl, and benzocyclohexyl carbocations 7 by azides produces spirocyclic aminodiazonium ions 8, which undergo 1,2-C-to-N rearrangement with loss of dinitrogen to produce benzo-fused iminium ions resulting from either aryl (9) or alkyl (10) mi...

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Veröffentlicht in:	Journal of organic chemistry 2000-10, Vol.65 (21), p.7158-7174
Hauptverfasser:	Pearson, William H, Fang, Wen-kui
Format:	Artikel
Sprache:	eng
Schlagworte:	Alkaloids - chemical synthesis Alkanes - chemical synthesis Amphibian Venoms - chemical synthesis Aza Compounds - chemical synthesis Bridged Bicyclo Compounds - chemical synthesis Cyclization Oxidation-Reduction Pyrroles - chemistry Quinolones - chemistry Stereoisomerism
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