Structural characterization of MAO and related aluminum complexes. 1. Solid-state (27)Al NMR with comparison to EFG tensors from ab initio molecular orbital calculations

Experimental and ab initio molecular orbital techniques are developed for study of aluminum species with large quadrupole coupling constants to test structural models for methylaluminoxanes (MAO). The techniques are applied to nitrogen- and oxygen-containing complexes of aluminum and to solid MAO is...

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Veröffentlicht in:	Journal of the American Chemical Society 2001-12, Vol.123 (48), p.12009-12017
Hauptverfasser:	Bryant, P L, Harwell, C R, Mrse, A A, Emery, E F, Gan, Z, Caldwell, T, Reyes, A P, Kuhns, P, Hoyt, D W, Simeral, L S, Hall, R W, Butler, L G
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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