Ammonium Ion Binding with Pyridine-Containing Crown Ethers

Dipyrido[24]crown-8 (DP24C8) has been synthesized and shown to form [2]pseudorotaxanes spontaneously with dibenzylammonium ions. These complexes, which have been demonstrated by 1H NMR spectroscopy to form faster in solution than when the macrocyclic polyether is dibenzo[24]crown-8 (DB24C8), are als...

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Veröffentlicht in:Organic letters 2000-09, Vol.2 (19), p.2947-2950
Hauptverfasser: Chang, Theresa, Heiss, Aaron M, Cantrill, Stuart J, Fyfe, Matthew C. T, Pease, Anthony R, Rowan, Stuart J, Stoddart, J. Fraser, White, Andrew J. P, Williams, David J
Format: Artikel
Sprache:eng
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