Chemistry of coordinated nitroxyl. Reagent-specific protonations of trans-Re(CO)(2)(NO)(PR(3))(2) (R = Ph, Cy) that give the neutral nitroxyl complexes cis,trans-ReCl(CO)(2)(NH=O)(PR(3))(2) or the cationic hydride complex [trans,trans-ReH(CO)(2)(NO)(PPh(3))(2)(+)][SO(3)CF(3)(-)]

The reactions of hydrochloric and triflic acids with the five-coordinate nitrosyl complexes trans-Re(CO)(2)(NO)(PR(3))(2) (2a, R = Ph; 2b, R = Cy) have been investigated. Reaction of anhydrous HCl with 2 results in a formal protonation of the nitrosyl ligand and addition of chloride to the metal, gi...

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Veröffentlicht in:	Inorganic chemistry 2001-11, Vol.40 (23), p.6039-6046
Hauptverfasser:	Southern, J S, Green, M T, Hillhouse, G L, Guzei, I A, Rheingold, A L
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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