Time Reversal and Molecular Properties

Time Reversal and Molecular Properties

Chemists regularly exploit point group symmetry in their analyses of molecular structure and properties but they rarely utilize time reversal symmetry. The time reversal operator T reverses the momenta and spins of all particles in a system and distinguishes properties which are even under T, such a...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Accounts of chemical research 2001-10, Vol.34 (10), p.781-789
Hauptverfasser: Barron, Laurence D., Buckingham, A. David
Format: Artikel
Sprache:eng
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
container_end_page 789
container_issue 10
container_start_page 781
container_title Accounts of chemical research
container_volume 34
creator Barron, Laurence D.
Buckingham, A. David
description Chemists regularly exploit point group symmetry in their analyses of molecular structure and properties but they rarely utilize time reversal symmetry. The time reversal operator T reverses the momenta and spins of all particles in a system and distinguishes properties which are even under T, such as the electric dipole moment, from those that are odd, such as the magnetic dipole moment. We review the role of T in quantum mechanics and discuss its application to the properties of molecules in electric and magnetic fields. Among the properties considered are natural and magnetic optical activity, magneto-chiral effects, antisymmetric Raman scattering, optical NMR and ESR, chirality, and absolute enantioselection.
doi_str_mv 10.1021/ar0100576
format Article
fullrecord <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_72195345</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>72195345</sourcerecordid><originalsourceid>FETCH-LOGICAL-a349t-ac065a3d2ba1fd3ca15295420f6d9f4b3d9162df8a8383413d4a955f5613a43d3</originalsourceid><addsrcrecordid>eNptkE1Lw0AQhhdRbK0e_AOSiwUP0f1O9miLX1C1tPG8TLMbSE2aupuI_ntXUurF08wwD-8MD0LnBF8TTMkNOEwwFok8QEMiKI55qtJDNMQYk9BzOkAn3q_DSLlMjtGAEImJknSIxllZ22hhP63zUEWwMdFzU9m8q8BFc9dsrWtL60_RUQGVt2e7OkJv93fZ9DGevT48TW9nMTCu2hhyLAUwQ1dACsNyCN8owSkupFEFXzGjiKSmSCFlKeOEGQ5KiEJIwoAzw0Zo3OduXfPRWd_quvS5rSrY2KbzOqFECcZFAK96MHeN984WeuvKGty3Jlj_StF7KYG92IV2q9qaP3JnIQBxD5S-tV_7Pbh3LROWCJ3Nl_plOcn4coE1D_xlz0Pu9brp3CY4-efwDyTMdNM</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>72195345</pqid></control><display><type>article</type><title>Time Reversal and Molecular Properties</title><source>ACS Publications</source><creator>Barron, Laurence D. ; Buckingham, A. David</creator><creatorcontrib>Barron, Laurence D. ; Buckingham, A. David</creatorcontrib><description>Chemists regularly exploit point group symmetry in their analyses of molecular structure and properties but they rarely utilize time reversal symmetry. The time reversal operator T reverses the momenta and spins of all particles in a system and distinguishes properties which are even under T, such as the electric dipole moment, from those that are odd, such as the magnetic dipole moment. We review the role of T in quantum mechanics and discuss its application to the properties of molecules in electric and magnetic fields. Among the properties considered are natural and magnetic optical activity, magneto-chiral effects, antisymmetric Raman scattering, optical NMR and ESR, chirality, and absolute enantioselection.</description><identifier>ISSN: 0001-4842</identifier><identifier>EISSN: 1520-4898</identifier><identifier>DOI: 10.1021/ar0100576</identifier><identifier>PMID: 11601962</identifier><language>eng</language><publisher>United States: American Chemical Society</publisher><ispartof>Accounts of chemical research, 2001-10, Vol.34 (10), p.781-789</ispartof><rights>Copyright © 2001 American Chemical Society</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-a349t-ac065a3d2ba1fd3ca15295420f6d9f4b3d9162df8a8383413d4a955f5613a43d3</citedby><cites>FETCH-LOGICAL-a349t-ac065a3d2ba1fd3ca15295420f6d9f4b3d9162df8a8383413d4a955f5613a43d3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://pubs.acs.org/doi/pdf/10.1021/ar0100576$$EPDF$$P50$$Gacs$$H</linktopdf><linktohtml>$$Uhttps://pubs.acs.org/doi/10.1021/ar0100576$$EHTML$$P50$$Gacs$$H</linktohtml><link.rule.ids>314,777,781,2752,27057,27905,27906,56719,56769</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/11601962$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Barron, Laurence D.</creatorcontrib><creatorcontrib>Buckingham, A. David</creatorcontrib><title>Time Reversal and Molecular Properties</title><title>Accounts of chemical research</title><addtitle>Acc. Chem. Res</addtitle><description>Chemists regularly exploit point group symmetry in their analyses of molecular structure and properties but they rarely utilize time reversal symmetry. The time reversal operator T reverses the momenta and spins of all particles in a system and distinguishes properties which are even under T, such as the electric dipole moment, from those that are odd, such as the magnetic dipole moment. We review the role of T in quantum mechanics and discuss its application to the properties of molecules in electric and magnetic fields. Among the properties considered are natural and magnetic optical activity, magneto-chiral effects, antisymmetric Raman scattering, optical NMR and ESR, chirality, and absolute enantioselection.</description><issn>0001-4842</issn><issn>1520-4898</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2001</creationdate><recordtype>article</recordtype><recordid>eNptkE1Lw0AQhhdRbK0e_AOSiwUP0f1O9miLX1C1tPG8TLMbSE2aupuI_ntXUurF08wwD-8MD0LnBF8TTMkNOEwwFok8QEMiKI55qtJDNMQYk9BzOkAn3q_DSLlMjtGAEImJknSIxllZ22hhP63zUEWwMdFzU9m8q8BFc9dsrWtL60_RUQGVt2e7OkJv93fZ9DGevT48TW9nMTCu2hhyLAUwQ1dACsNyCN8owSkupFEFXzGjiKSmSCFlKeOEGQ5KiEJIwoAzw0Zo3OduXfPRWd_quvS5rSrY2KbzOqFECcZFAK96MHeN984WeuvKGty3Jlj_StF7KYG92IV2q9qaP3JnIQBxD5S-tV_7Pbh3LROWCJ3Nl_plOcn4coE1D_xlz0Pu9brp3CY4-efwDyTMdNM</recordid><startdate>20011001</startdate><enddate>20011001</enddate><creator>Barron, Laurence D.</creator><creator>Buckingham, A. David</creator><general>American Chemical Society</general><scope>BSCLL</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope></search><sort><creationdate>20011001</creationdate><title>Time Reversal and Molecular Properties</title><author>Barron, Laurence D. ; Buckingham, A. David</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a349t-ac065a3d2ba1fd3ca15295420f6d9f4b3d9162df8a8383413d4a955f5613a43d3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2001</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Barron, Laurence D.</creatorcontrib><creatorcontrib>Buckingham, A. David</creatorcontrib><collection>Istex</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><jtitle>Accounts of chemical research</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Barron, Laurence D.</au><au>Buckingham, A. David</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Time Reversal and Molecular Properties</atitle><jtitle>Accounts of chemical research</jtitle><addtitle>Acc. Chem. Res</addtitle><date>2001-10-01</date><risdate>2001</risdate><volume>34</volume><issue>10</issue><spage>781</spage><epage>789</epage><pages>781-789</pages><issn>0001-4842</issn><eissn>1520-4898</eissn><abstract>Chemists regularly exploit point group symmetry in their analyses of molecular structure and properties but they rarely utilize time reversal symmetry. The time reversal operator T reverses the momenta and spins of all particles in a system and distinguishes properties which are even under T, such as the electric dipole moment, from those that are odd, such as the magnetic dipole moment. We review the role of T in quantum mechanics and discuss its application to the properties of molecules in electric and magnetic fields. Among the properties considered are natural and magnetic optical activity, magneto-chiral effects, antisymmetric Raman scattering, optical NMR and ESR, chirality, and absolute enantioselection.</abstract><cop>United States</cop><pub>American Chemical Society</pub><pmid>11601962</pmid><doi>10.1021/ar0100576</doi><tpages>9</tpages></addata></record>
fulltext fulltext
identifier ISSN: 0001-4842
ispartof Accounts of chemical research, 2001-10, Vol.34 (10), p.781-789
issn 0001-4842
1520-4898
language eng
recordid cdi_proquest_miscellaneous_72195345
source ACS Publications
title Time Reversal and Molecular Properties
url https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-20T07%3A05%3A06IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Time%20Reversal%20and%20Molecular%20Properties&rft.jtitle=Accounts%20of%20chemical%20research&rft.au=Barron,%20Laurence%20D.&rft.date=2001-10-01&rft.volume=34&rft.issue=10&rft.spage=781&rft.epage=789&rft.pages=781-789&rft.issn=0001-4842&rft.eissn=1520-4898&rft_id=info:doi/10.1021/ar0100576&rft_dat=%3Cproquest_cross%3E72195345%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=72195345&rft_id=info:pmid/11601962&rfr_iscdi=true