An unexpected Paternò-Büchi reaction in the crystalline state

[reaction: see text]. The solution and solid-state photochemistry of a series of aryl 1-phenylcyclopentyl ketones (1) was investigated. While typical Norrish type I products were formed in solution, irradiation of crystals of 1 afforded the novel oxetanes 3 and 4 regiospecifically. The formation of...

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Veröffentlicht in:	Organic letters 2001-10, Vol.3 (21), p.3361-3364
Hauptverfasser:	Kang, T, Scheffer, J R
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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